Synthesis, characterization and structure effects on extractability and selectivity of N,N′-bis(salicylaldehydene) - 1,4-bIS-(m-ami̇nophenoxy) butane towards some divalent cations

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dc.contributor.authorZiyadanoğulları, Berrin
dc.contributor.authorCeviziçi, Deniz
dc.contributor.authorTemel, Hamdi
dc.contributor.authorGüzel, Remziye
dc.contributor.orcid0000-0002-9004-8993
dc.date.accessioned2024-04-24T15:59:18Z
dc.date.available2024-04-24T15:59:18Z
dc.date.issued2007
dc.departmentDicle Üniversitesi, Fen Fakültesi, Kimya Bölümüen_US
dc.description.abstractThe extraction of copper(II), nickel(II) and cobalt(II) from the aqueous phase with N,N'-bis(saticylaldehydene)-1,4-bis-(in-aminophenoxy)butane (NIAS), which was synthesized from 1,4-bis(m-aminophenoxy)butane and salicylaldehyde, was studied. Microanalytical data, elemental analysis, UV-visible H-1 and C-13 n.m.r. spectra and IR-spectra were used to confirm the structures. The extractability and selectivity of divalent cations were evaluated as a function of relationship between distribution ratio of the metal and pH or ligand concentration. Cu+2 showed the highest extractability and selectivity at pH 6.0, whereas Ni+2 and Co+2 showed at pH 9.2. The stoichiometries of the compounds formed were estimated to be CuL, CoL, NiL, where L is N,N'-bis(salicylaldehydene)-1,4-bis-(m-aminophenoxy)butane. It was concluded that MAS can effectively be used in solvent extraction of copper(II), nickel(II) and cobalt(II) from the aqeous phase to the organic phase.en_US
dc.identifier.citationZiyadanoğulları, B., Ceviziçi, D., Temel, H. ve Güzel, R. (2007). Synthesis, characterization and structure effects on extractability and selectivity of N,N′-bis(salicylaldehydene) - 1,4-bIS-(m-ami̇nophenoxy) butane towards some divalent cations. Annali Di Chimica, 97(5-6), 287-294.
dc.identifier.doi10.1002/adic.200790014
dc.identifier.endpage294en_US
dc.identifier.issn0003-4592
dc.identifier.issue5-6en_US
dc.identifier.pmid17696007
dc.identifier.scopus2-s2.0-34249827230
dc.identifier.scopusqualityN/A
dc.identifier.startpage287en_US
dc.identifier.urihttps://doi.org/10.1002/adic.200790014
dc.identifier.urihttps://hdl.handle.net/11468/13947
dc.identifier.urihttps://onlinelibrary.wiley.com/doi/epdf/10.1002/adic.200790014
dc.identifier.volume97en_US
dc.identifier.wosWOS:000247150200002
dc.identifier.wosqualityQ4
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.indekslendigikaynakPubMed
dc.institutionauthorZiyadanoğulları, Berrin
dc.institutionauthorCeviziçi, Deniz
dc.institutionauthorTemel, Hamdi
dc.institutionauthorGüzel, Remziye
dc.language.isoenen_US
dc.publisherWiley-V C H Verlag Gmbhen_US
dc.relation.ispartofAnnali Di Chimica
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subject[No Keyword]en_US
dc.titleSynthesis, characterization and structure effects on extractability and selectivity of N,N′-bis(salicylaldehydene) - 1,4-bIS-(m-ami̇nophenoxy) butane towards some divalent cationsen_US
dc.titleSynthesis, characterization and structure effects on extractability and selectivity of N,N?-bis(salicylaldehydene) - 1,4-bIS-(m-ami?nophenoxy) butane towards some divalent cations
dc.typeArticleen_US

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