Synthesis, characterization and structure effects on extractability and selectivity of N,N′-bis(salicylaldehydene) - 1,4-bIS-(m-ami̇nophenoxy) butane towards some divalent cations
Yükleniyor...
Tarih
2007
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Wiley-V C H Verlag Gmbh
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
The extraction of copper(II), nickel(II) and cobalt(II) from the aqueous phase with N,N'-bis(saticylaldehydene)-1,4-bis-(in-aminophenoxy)butane (NIAS), which was synthesized from 1,4-bis(m-aminophenoxy)butane and salicylaldehyde, was studied. Microanalytical data, elemental analysis, UV-visible H-1 and C-13 n.m.r. spectra and IR-spectra were used to confirm the structures. The extractability and selectivity of divalent cations were evaluated as a function of relationship between distribution ratio of the metal and pH or ligand concentration. Cu+2 showed the highest extractability and selectivity at pH 6.0, whereas Ni+2 and Co+2 showed at pH 9.2. The stoichiometries of the compounds formed were estimated to be CuL, CoL, NiL, where L is N,N'-bis(salicylaldehydene)-1,4-bis-(m-aminophenoxy)butane. It was concluded that MAS can effectively be used in solvent extraction of copper(II), nickel(II) and cobalt(II) from the aqeous phase to the organic phase.
Açıklama
Anahtar Kelimeler
[No Keyword]
Kaynak
Annali Di Chimica
WoS Q Değeri
Q4
Scopus Q Değeri
N/A
Cilt
97
Sayı
5-6
Künye
Ziyadanoğulları, B., Ceviziçi, D., Temel, H. ve Güzel, R. (2007). Synthesis, characterization and structure effects on extractability and selectivity of N,N′-bis(salicylaldehydene) - 1,4-bIS-(m-ami̇nophenoxy) butane towards some divalent cations. Annali Di Chimica, 97(5-6), 287-294.
