Preparation and characterization of activated carbon from hydrochar by hydrothermal carbonization of chickpea stem: an application in methylene blue removal by RSM optimization

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dc.authorid0000-0003-1451-1023en_US
dc.contributor.authorGenli, Nasrettin
dc.contributor.authorKutluay, Sinan
dc.contributor.authorBaytar, Orhan
dc.contributor.authorŞahin, Ömer
dc.date.accessioned2022-08-23T13:04:16Z
dc.date.available2022-08-23T13:04:16Z
dc.date.issued2022en_US
dc.departmentDicle Üniversitesi, Diyarbakır Teknik Bilimler Meslek Yüksekokulu, Kimya ve Kimyasal İşleme Teknolojileri Bölümüen_US
dc.descriptionWOS:000653060100001
dc.descriptionPMID: 34024213
dc.description.abstractHerein, mesoporous activated carbon (AC) was prepared through potassium hydroxide (KOH) activation of hydrochar derived from the hydrothermal carbonization (HTC) of chickpea stem (CS), and successfully applied to remove methylene blue (MB) dye from aqueous solutions in a batch system. The HTC-CSAC was prepared depending on different impregnation ratios (hydrochar:KOH, 50-150%), impregnation times (12-48h), activation temperatures (400-600 degrees C) and activation times (30-60min). To define HTC-CSAC, various analytical techniques such as iodine adsorption number (IAN), Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and Brunauer-Emmett-Teller (BET) were used. In the removal process of MB by the best HTC-CSAC with a high IAN of 887mg g(-1) obtained under conditions including impregnation ratio of 70%, activation time of 45min, activation temperature of 600 degrees C and impregnation time of 24h, the effects of adsorption parameters such as pH factor (2-10), adsorbent dosage (50-100mg), initial MB concentration (40-80mg/L) and contact time (90-180min) were studied. Besides, a detailed evaluation of the adsorption mechanism for the removal of MB by HTC-CSAC was performed. The Langmuir model indicated the best isotherm data correlation, with a maximum monolayer adsorption capacity (Q(max)) of 96.15mg g(-1). The adsorption isotherm findings demonstrated that the MB removal process is feasible, and that this process takes place through the physical interaction mechanism. Additionally, the HTC-CSAC adsorbent exhibited a high regeneration and reuse performance in MB removal. After five consecutive adsorption-desorption cycles, HTC-CSAC maintained the reuse efficiency of 77.86%. As a result, the prepared HTC-CSAC with a high BET surface area of 455m(2) g(-1) and an average pore diameter of 105 angstrom could be recommended as a promising and reusable adsorbent in the treatment of synthetic dyes in wastewaters.en_US
dc.identifier.citationGenli, N., Kutluay, S., Baytar, O. ve Şahin, Ö. (2022). Preparation and characterization of activated carbon from hydrochar by hydrothermal carbonization of chickpea stem: an application in methylene blue removal by RSM optimization. International Journal of Phytoremediation, 24(1), 88-100. https://doi.org/10.1080/15226514.2021.1926911en_US
dc.identifier.doi10.1080/15226514.2021.1926911
dc.identifier.endpage100en_US
dc.identifier.issn1522-6514
dc.identifier.issn1549-7879
dc.identifier.issue1en_US
dc.identifier.pmid34024213
dc.identifier.scopus2-s2.0-85106324690
dc.identifier.scopusqualityQ1
dc.identifier.startpage88en_US
dc.identifier.urihttps://www.tandfonline.com/doi/full/10.1080/15226514.2021.1926911
dc.identifier.urihttps://hdl.handle.net/11468/10249
dc.identifier.volume24en_US
dc.identifier.wosWOS:000653060100001
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.indekslendigikaynakPubMed
dc.institutionauthorGenli, Nasrettin
dc.language.isoenen_US
dc.publisherTaylor & Francisen_US
dc.relation.ispartofInternational Journal of Phytoremediation
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/embargoedAccessen_US
dc.subjectActivated carbonen_US
dc.subjectHydrothermal carbonization (HTC)en_US
dc.subjectHydrocharen_US
dc.subjectMethylene blue removalen_US
dc.subjectIsotherm modelsen_US
dc.subjectRegenerationen_US
dc.subjectReuseen_US
dc.titlePreparation and characterization of activated carbon from hydrochar by hydrothermal carbonization of chickpea stem: an application in methylene blue removal by RSM optimizationen_US
dc.titlePreparation and characterization of activated carbon from hydrochar by hydrothermal carbonization of chickpea stem: an application in methylene blue removal by RSM optimization
dc.typeArticleen_US

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