Synthesis and reactions of new 2-hydroxymethyldimethoxyindoles

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dc.contributor.authorBingul, Murat
dc.contributor.authorKumar, Naresh
dc.contributor.authorBlack, David StC
dc.date.accessioned2024-04-24T16:18:26Z
dc.date.available2024-04-24T16:18:26Z
dc.date.issued2016
dc.departmentDicle Üniversitesien_US
dc.description.abstractLithium aluminium hyride was used as a reducing agent to prepare a range of 2-hydroxymethyldimethoxyindole derivatives from the related methyl esters. Acid-catalysed reactions of these indole-2-methanols yielded indolo-cyclotriveratrylenes linked through C-2 and C-3. The related indole-2-carbaldehydes were prepared via oxidation of the indole-2-methanols in the presence of manganese dioxide. Vilsmeier formylation was explored to prepare new formylated indole-2-carbaldehydes. Furthermore, the treatment of indole-2-carbaldehydes with nitromethane led to the formation of 2-nitrovinylindoles. (C) 2015 Elsevier Ltd. All rights reserved.en_US
dc.identifier.doi10.1016/j.tet.2015.11.038
dc.identifier.endpage239en_US
dc.identifier.issn0040-4020
dc.identifier.issue1en_US
dc.identifier.scopus2-s2.0-84949625528
dc.identifier.scopusqualityQ3
dc.identifier.startpage234en_US
dc.identifier.urihttps://doi.org/10.1016/j.tet.2015.11.038
dc.identifier.urihttps://hdl.handle.net/11468/16089
dc.identifier.volume72en_US
dc.identifier.wosWOS:000367276300026
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoenen_US
dc.publisherPergamon-Elsevier Science Ltden_US
dc.relation.ispartofTetrahedron
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subject2-Hydroxydimethoxyindolesen_US
dc.subjectReductionen_US
dc.subjectOxidationen_US
dc.subjectIndolo-Cyclotriveratryleneen_US
dc.subject2-Nitrovinylindoleen_US
dc.titleSynthesis and reactions of new 2-hydroxymethyldimethoxyindolesen_US
dc.titleSynthesis and reactions of new 2-hydroxymethyldimethoxyindoles
dc.typeArticleen_US

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