Crystal structure of 2-[4-(4-chlorophenyl)-1-(4-methoxyphenyl)-2-oxoazetidin-3-yl]benzo[de]isoquinoline-1,3-dione dimethyl sulfoxide monosolvate

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dc.contributor.authorCelik, Ismail
dc.contributor.authorAkkurt, Mehmet
dc.contributor.authorJarrahpour, Aliasghar
dc.contributor.authorRad, Javad Ameri
dc.contributor.authorCelik, Omer
dc.date.accessioned2024-04-24T17:08:42Z
dc.date.available2024-04-24T17:08:42Z
dc.date.issued2015
dc.departmentDicle Üniversitesien_US
dc.description.abstractIn the title solvated compound, C28H19N2O4 center dot C2H6OS, the central beta-lactam ring is almost planar (r.m.s. deviation = 0.002 angstrom). It makes dihedral angles of 1.92 (11), 83.23 (12) and 74.90 (10)degrees with the methoxy-and chlorophenyl rings and the ring plane of the 1H-benzo[de]isoquinoline-1,3(2H)-dione group [maximum deviation = 0.089 (1)], respectively. An intramolecular C-H center dot center dot center dot O hydrogen bond closes an S(6) ring and helps to establish the near coplanarity of the beta-lactam and methoxybenzene rings. In the crystal, the components are linked by C-H center dot center dot center dot O hydrogen bonds, C-H center dot center dot center dot pi interactions and aromatic pi-pi stacking interactions [centroid-to-centroid distances = 3.6166 (10) and 3.7159 (10) angstrom], resulting in a three-dimensional network, The dimethyl sulfoxide solvent molecule is disordered over two sets of sites in a 0.847 (2):0.153 (2) ratio.en_US
dc.description.sponsorshipShiraz University Research Council [93-GR-SC-23]en_US
dc.description.sponsorshipThe authors are indebted to the X-ray laboratory of Dicle University Scientific and Technological Applied and Research Center, Diyarbakir, Turkey, for use of the X-ray diffractometer. AJ and JAR thank the Shiraz University Research Council for financial support (grant No. 93-GR-SC-23).en_US
dc.identifier.doi10.1107/S2056989015001425
dc.identifier.endpageU587en_US
dc.identifier.issn2056-9890
dc.identifier.pmid25878867
dc.identifier.scopus2-s2.0-84928167430
dc.identifier.scopusqualityQ3
dc.identifier.startpageO129en_US
dc.identifier.urihttps://doi.org/10.1107/S2056989015001425
dc.identifier.urihttps://hdl.handle.net/11468/17428
dc.identifier.volume71en_US
dc.identifier.wosWOS:000369971500055
dc.identifier.wosqualityN/A
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.indekslendigikaynakPubMed
dc.language.isoenen_US
dc.publisherInt Union Crystallographyen_US
dc.relation.ispartofActa Crystallographica Section E-Crystallographic Communications
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectCrystal Structureen_US
dc.subjectBeta-Lactam Ringen_US
dc.subject1h-Benzo[De]Isoquinoline-1,3(2h)-Dione Groupen_US
dc.subjectDisorderen_US
dc.subjectAzetidin-2-Onesen_US
dc.titleCrystal structure of 2-[4-(4-chlorophenyl)-1-(4-methoxyphenyl)-2-oxoazetidin-3-yl]benzo[de]isoquinoline-1,3-dione dimethyl sulfoxide monosolvateen_US
dc.titleCrystal structure of 2-[4-(4-chlorophenyl)-1-(4-methoxyphenyl)-2-oxoazetidin-3-yl]benzo[de]isoquinoline-1,3-dione dimethyl sulfoxide monosolvate
dc.typeArticleen_US

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