Crystal structure of 3-(4-chlorophenoxy)4-(2-nitrophenyl)azetidin-2-one with an unknown solvate

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dc.contributor.authorCelikesir, Sevim Turktekin
dc.contributor.authorAkkurt, Mehmet
dc.contributor.authorJarrahpour, Aliasghar
dc.contributor.authorShafie, Habib Allah
dc.contributor.authorCelik, Omer
dc.date.accessioned2024-04-24T17:08:41Z
dc.date.available2024-04-24T17:08:41Z
dc.date.issued2015
dc.departmentDicle Üniversitesien_US
dc.description.abstractIn the title compound, C15H11ClN2O4, the central beta-lactam ring is approximately planar [maximum deviation = 0.044 (2) angstrom for the N atom from the mean plane] and subtends dihedral angles of 61.17 (11) and 40.21 (12)degrees, respectively, with the nitro and chlorobenzene rings. Both substituents lie to the same side of the beta-lactam core. In the crystal, N-H center dot center dot center dot O hydrogen bonds link the molecules into C(4) chains propagating in [010]. The chains are cross-linked by C-H center dot center dot center dot O and weak C-H center dot center dot center dot pi interactions, generating a three-dimensional network. The solvent molecules were found to be highly disordered and their contribution to the scattering was removed with the SQUEEZE procedure in PLATON [Spek (2009). Acta Cryst. D65, 148-155], which indicated a solvent cavity of volume 318 angstrom(3) containing approximately 114 electrons. These solvent molecules are not considered in the given chemical formula and other crystal data.en_US
dc.identifier.doi10.1107/S2056989014025845
dc.identifier.endpage+en_US
dc.identifier.issn2056-9890
dc.identifier.pmid25705514
dc.identifier.scopus2-s2.0-84928129062
dc.identifier.scopusqualityQ3
dc.identifier.startpageO8en_US
dc.identifier.urihttps://doi.org/10.1107/S2056989014025845
dc.identifier.urihttps://hdl.handle.net/11468/17426
dc.identifier.volume71en_US
dc.identifier.wosWOS:000369968500015
dc.identifier.wosqualityN/A
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.indekslendigikaynakPubMed
dc.language.isoenen_US
dc.publisherInt Union Crystallographyen_US
dc.relation.ispartofActa Crystallographica Section E-Crystallographic Communications
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectCrystal Structureen_US
dc.subjectBeta-Lactam Ringen_US
dc.subjectC(4) Chainen_US
dc.subjectHydrogen Bondingen_US
dc.subjectN-Unsubstituted 2-Azetidinoneen_US
dc.subjectHydrogen Bondsen_US
dc.subjectC-H Center Dot Center Dot Center Dot Pi Interactionsen_US
dc.titleCrystal structure of 3-(4-chlorophenoxy)4-(2-nitrophenyl)azetidin-2-one with an unknown solvateen_US
dc.titleCrystal structure of 3-(4-chlorophenoxy)4-(2-nitrophenyl)azetidin-2-one with an unknown solvate
dc.typeArticleen_US

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