Nanozirconia supported ruthenium(0) nanoparticles: Highly active and reusable catalyst in hydrolytic dehydrogenation of ammonia borane

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dc.contributor.authorTonbul, Yalcin
dc.contributor.authorAkbayrak, Serdar
dc.contributor.authorOzkar, Saim
dc.date.accessioned2024-04-24T16:15:01Z
dc.date.available2024-04-24T16:15:01Z
dc.date.issued2018
dc.departmentDicle Üniversitesien_US
dc.description.abstractNanozirconia supported ruthenium(0) nanoparticles (Ru-0/ZrO2) were prepared by impregnation of ruthenium(III) cations on the surface of zirconia followed by their reduction with sodium borohydride at room temperature. Ru-0/ZrO2 was isolated from the reaction solution by centrifugation and characterized by ICP-OES, XRD, TEM, SEM EDS and XPS techniques. All the results reveal that ruthenium(0) nanoparticles were successfully supported on zirconia and the resulting Ru-0/ZrO2 is a highly active and reusable catalyst for hydrogen generation from the hydrolysis of ammonia borane with a turnover frequency value of 173 min(-1) at 25 degrees C. The reusability and catalytic lifetime tests reveal that Ru-0/ZrO2 is still active in the subsequent runs of hydrolysis of ammonia borane preserving 67% of the initial catalytic activity even after the fifth run and Ru-0/ZrO2 provides 72,500 turnovers (mol H-2/mol Ru) before deactivation at 25 degrees C. Our report also includes the results of kinetic studies depending on the catalyst concentration and temperature to determine the activation energy (E-a = 58 2 kJ/mol) for hydrolytic dehydrogenation of AB. (C) 2017 Elsevier Inc. All rights reserved.en_US
dc.description.sponsorshipTurkish Academy of Sciences; Dicle University BAP [ZGEF.17.013]en_US
dc.description.sponsorshipPartial support by Turkish Academy of Sciences and Dicle University BAP with a project number of ZGEF.17.013 is gratefully acknowledged. We thank to the METU Central Laboratories for the TEM, XPS, ICP-OES, BET analysis.en_US
dc.identifier.doi10.1016/j.jcis.2017.11.037
dc.identifier.endpage294en_US
dc.identifier.issn0021-9797
dc.identifier.issn1095-7103
dc.identifier.pmid29156236en_US
dc.identifier.scopus2-s2.0-85034651273en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage287en_US
dc.identifier.urihttps://doi.org/10.1016/j.jcis.2017.11.037
dc.identifier.urihttps://hdl.handle.net/11468/15595
dc.identifier.volume513en_US
dc.identifier.wosWOS:000428834900031
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.indekslendigikaynakPubMed
dc.language.isoenen_US
dc.publisherAcademic Press Inc Elsevier Scienceen_US
dc.relation.ispartofJournal of Colloid and Interface Scienceen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectZirconiaen_US
dc.subjectRuthenium Nanoparticlesen_US
dc.subjectAmmonia Boraneen_US
dc.subjectHydrogen Generationen_US
dc.titleNanozirconia supported ruthenium(0) nanoparticles: Highly active and reusable catalyst in hydrolytic dehydrogenation of ammonia boraneen_US
dc.typeArticleen_US

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