P-N bond cleavage during the insertion of carbon fragments into PIII-N bonds in bis(diphenylphosphino) amines

dc.contributor.authorBiricik, Nermin
dc.contributor.authorKayan, Cezmi
dc.contributor.authorGümgüm, Bahattin
dc.contributor.orcid0000-0001-5700-8546
dc.date.accessioned2024-04-24T15:59:24Z
dc.date.available2024-04-24T15:59:24Z
dc.date.issued2014
dc.departmentDicle Üniversitesi, Fen Fakültesi, Kimya Bölümüen_US
dc.description.abstractThe reaction of tertiary amine functionalized phosphines with aromatic and aliphatic aldehydes gives insertion of carbon fragments into the P-III-N bonds or P-III-N bond cleavage. The reaction of bis(diphenylphosphino) amines, la lc, with two equiv. of aldehydes in toluene afforded the P-III-N bond inserted products, 2a-4a, 4b-6b, and 3c-5c, in moderate-to-good yield. The products were characterized by IR, H-1- and P-31-NMR spectroscopy and elemental analysis.en_US
dc.description.sponsorshipMedical Research Center Program through National Research Foundation of Korea [2010-0029480]en_US
dc.description.sponsorshipThis study was financially supported by the Medical Research Center Program through the National Research Foundation of Korea (2010-0029480).en_US
dc.identifier.citationBiricik, N., Kayan, C. ve Gümgüm, B. (2014). P-N bond cleavage during the insertion of carbon fragments into PIII-N bonds in bis(diphenylphosphino) amines. Helvetica Chimica Acta, 97(8), 1158-1164.
dc.identifier.doi10.1002/hlca.201400074
dc.identifier.endpage1164en_US
dc.identifier.issn0018-019X
dc.identifier.issn1522-2675
dc.identifier.issue8en_US
dc.identifier.scopus2-s2.0-84907339491
dc.identifier.scopusqualityQ3
dc.identifier.startpage1158en_US
dc.identifier.urihttps://doi.org/10.1002/hlca.201400074
dc.identifier.urihttps://hdl.handle.net/11468/14042
dc.identifier.urihttps://onlinelibrary.wiley.com/doi/10.1002/hlca.201400074
dc.identifier.volume97en_US
dc.identifier.wosWOS:000341295000015
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthorBiricik, Nermin
dc.institutionauthorKayan, Cezmi
dc.institutionauthorGümgüm, Bahattin
dc.language.isoenen_US
dc.publisherWiley-V C H Verlag Gmbhen_US
dc.relation.ispartofHelvetica Chimica Acta
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subject[No Keyword]en_US
dc.titleP-N bond cleavage during the insertion of carbon fragments into PIII-N bonds in bis(diphenylphosphino) aminesen_US
dc.titleP-N bond cleavage during the insertion of carbon fragments into PIII-N bonds in bis(diphenylphosphino) amines
dc.typeArticleen_US

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