P-N bond cleavage during the insertion of carbon fragments into PIII-N bonds in bis(diphenylphosphino) amines
Yükleniyor...
Tarih
2014
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Wiley-V C H Verlag Gmbh
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
The reaction of tertiary amine functionalized phosphines with aromatic and aliphatic aldehydes gives insertion of carbon fragments into the P-III-N bonds or P-III-N bond cleavage. The reaction of bis(diphenylphosphino) amines, la lc, with two equiv. of aldehydes in toluene afforded the P-III-N bond inserted products, 2a-4a, 4b-6b, and 3c-5c, in moderate-to-good yield. The products were characterized by IR, H-1- and P-31-NMR spectroscopy and elemental analysis.
Açıklama
Anahtar Kelimeler
[No Keyword]
Kaynak
Helvetica Chimica Acta
WoS Q Değeri
Q3
Scopus Q Değeri
Q3
Cilt
97
Sayı
8
Künye
Biricik, N., Kayan, C. ve Gümgüm, B. (2014). P-N bond cleavage during the insertion of carbon fragments into PIII-N bonds in bis(diphenylphosphino) amines. Helvetica Chimica Acta, 97(8), 1158-1164.
