Synthesis, spectroscopic and electrochemical investigations of two vic-dioximes and their mononuclear Ni(II), Cu(II) and Co(II) metal complexes containing morpholine group
Yükleniyor...
Tarih
2006
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Wiley-V C H Verlag Gmbh
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
Two vic-dioxime ligands (LxH2) containing morpholine group have been synthesized from 4-[2-(dimethylaminoethyl)] morpholine with anti-phenylchloroglyoxime or anti-monochloroglyoxime in absolute THF at -15 degrees C. Reaction of two vic-dioxime ligands with MCl2 center dot nH(2)O (M: Ni, Cu or Co and n=2 or 6) salts in 1 : 2 molar ratio afforded metal complexes of type [M(LxH)(2)] or [M(LxH)(2)center dot 2H(2)O]. All of metal complexes are non-electrolytes as shown by their molar conductivities (Lambda(m)) in DMF (dimethyl formamide) at 10(-3) mol.L-1. Structures of the ligands and metal complexes have been solved by elemental analyses, FT-IR, UV-Vis, H-1 NMR and C-13 NMR, magnetic susceptibility measurements, molar conductivity measurements. Furthermore, redox properties of the metal complexes were investigated by cyclic voltammetry.
Açıklama
Anahtar Kelimeler
Morpholine, Electrochemistry, Dioxime, Structure, Metal complex, Cyclic voltammetry
Kaynak
Chinese Journal of Chemistry
WoS Q Değeri
Q3
Scopus Q Değeri
Q1
Cilt
24
Sayı
11
Künye
Kılıç, A., Taş, E., Gümgüm, B. ve Yımaz, İ. (2006). Synthesis, spectroscopic and electrochemical investigations of two vic-dioximes and their mononuclear Ni(II), Cu(II) and Co(II) metal complexes containing morpholine group. Chinese Journal of Chemistry, 24(11), 1599-1604.
