A geochemical study of bitumen residues on ceramics excavated from Early Bronze age graves (3000-2900 BCE) at Basur Hoyuk in SE Turkey

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Tarih

2018

Dergi Başlığı

Dergi ISSN

Cilt Başlığı

Yayıncı

Pergamon-Elsevier Science Ltd

Erişim Hakkı

info:eu-repo/semantics/closedAccess

Özet

Eight black residues, scraped from outer surfaces of painted ceramics, unearthed from graves 1-3 at Basur Hoyuk (SE Turkey), were analysed by geochemical techniques in order to characterize bitumens and to try to identify their source. Ceramics are dated from the Early Bronze period (3100-2900 BCE). The black organic matter was indeed identified as bitumen, but its source has not been discovered despite its comparison with several oil seeps from the area. The bitumen at Basur Hoyuk does not match the bitumens analyzed at Kavusan Hoyuk, Salat Hoyuk, Hakemi Use and Kuriki Hoyuk which are Cretaceous in origin and likely imported from the Eruh tars deposit. The stable carbon isotope values of their asphaltene fraction suggest a Silurian origin, however the occurrence of the 18 alpha(H)-oleanane emphasized a younger source, i.e. Tertiary or Cretaceous. Our interpretation favours the mixture of two oils, a Silurian age and a Tertiary-Cretaceous age. This mixture may occur geologically, due to the uptake of a Tertiary signal by a Silurian oil along its migration route to the surface. It may also be a consequence of human activity carried out by the inhabitants at the mortuary ceremony where the bituminous mixture has been applied to ceramics, prior to their deposit in the graves. The oil seep character of the archaeological bitumen at Basur Hoyuk and the lack of obvious oxidation suggest the following explanation: freshly collected oil seeps were splashed on ceramics as ritual practices and the tarry potteries were then buried and therefore sealed. The fast burial prevented the bitumen from any oxidative alteration. (c) 2017 Elsevier Ltd. All rights reserved.

Açıklama

Anahtar Kelimeler

Archaeological Bitumen, Pottery, Graves, Early Bronze Age, Steranes, Terpanes, Oil Seeps, Silurian, Cretaceous

Kaynak

Organic Geochemistry

WoS Q Değeri

Q2

Scopus Q Değeri

Q2

Cilt

115

Sayı

Künye