Crystal structure of N,N?-bis(dodecyl)diaza-18-crown-6 complexed sodium perchlorate

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dc.contributor.authorOzbey, S
dc.contributor.authorKendi, E
dc.contributor.authorHosgoren, H
dc.contributor.authorTogrul, M
dc.date.accessioned2024-04-24T16:19:08Z
dc.date.available2024-04-24T16:19:08Z
dc.date.issued1998
dc.departmentDicle Üniversitesien_US
dc.description.abstractThe crystal structure of a new complex of a diaza-crown ether having two side arms has been determined from X-ray diffraction data. The compound crystallizes in space group P (1) over bar with cell dimensions a = 9.982(1), b = 10.685(1), c = 20.376(2)Angstrom, alpha = 81.09(1), beta = 80.92(1), gamma 88.43(1)(0), Z = 2. The structure has been solved by direct methods and refined to the final R value of 0.053 for 3458 observed reflections and 424 parameters. The diaza-18-crown-6 ligand adopts an approximate D-3d conformation. The Na+ ion is held inside the molecular cavity of this macroring ligand and a ClO4- oxygen coordinates with Na+. The average Na-O (18-crown-6) and Na-N bond lengths are 2.426(4) and 2.786(5)Angstrom, respectively; the Na-O (ClO4-) bond length is 2.472(4)Angstrom. The mean cavity radius is 1.10 Angstrom and the N ... N nonbonding distance is 4.605(6)Angstrom.en_US
dc.identifier.doi10.1023/A:1007926108938
dc.identifier.endpage87en_US
dc.identifier.issn0923-0750
dc.identifier.issue1en_US
dc.identifier.scopus2-s2.0-0031605054
dc.identifier.scopusqualityN/A
dc.identifier.startpage79en_US
dc.identifier.urihttps://doi.org/10.1023/A:1007926108938
dc.identifier.urihttps://hdl.handle.net/11468/16413
dc.identifier.volume30en_US
dc.identifier.wosWOS:000072380400008
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoenen_US
dc.publisherSpringeren_US
dc.relation.ispartofJournal of Inclusion Phenomena and Molecular Recognition in Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectCrown Etheren_US
dc.subjectMacrocyclesen_US
dc.subjectDiaza-18-Crown-6en_US
dc.subjectSodium Complexen_US
dc.titleCrystal structure of N,N?-bis(dodecyl)diaza-18-crown-6 complexed sodium perchlorateen_US
dc.titleCrystal structure of N,N?-bis(dodecyl)diaza-18-crown-6 complexed sodium perchlorate
dc.typeArticleen_US

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