Applications of transition metal complexes containing aminophosphine ligand to transfer hydrogenation of ketones

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dc.contributor.authorAydemir, Murat
dc.contributor.authorBaysal, Akın
dc.contributor.authorTurgut, Yılmaz
dc.contributor.orcid0000-0001-7294-6792
dc.date.accessioned2024-04-24T15:59:18Z
dc.date.available2024-04-24T15:59:18Z
dc.date.issued2011
dc.departmentDicle Üniversitesi, Fen Fakültesi, Kimya Bölümüen_US
dc.description.abstractHydrogen transfer reduction processes are attracting increasing interest from synthetic chemists in view of their operational simplicity. Reaction of [Ph2PNHCH2-C4H3S] with [Ru(eta(6)-benzene)(mu-Cl)Cl](2), [Rh(mu-Cl)(cod)](2) and [Ir(eta(5)-C5Me5)(mu-Cl)Cl](2) gave a range of new monodendate complexes [Ru(Ph2PNHCH2-C4H3S)(eta(6)-benzene)Cl-2], 1, [Rh(Ph2PNHCH2-C4H3S)(cod)Cl], 2, and [Ir(Ph2PNHCH2-C4H3S)(eta(5)-C5Me5)Cl-2], 3, respectively. All new complexes were fully characterized by analytical and spectroscopic methods. H-1-P-31 NMR, H-1-C-13 HETCOR or H-1-H-1 COSY correlation experiments were used to confirm the spectral assignments. 1-3 are suitable catalyst precursors for the transfer hydrogenation of acetophenone derivatives. Notably [Ru(Ph2PNHCH2-C4H3S)(eta(6)-benzene) Cl-2], 1, acts as an excellent catalyst, giving the corresponding alcohols in 98-99% yields in 30 min at 82 degrees C (TOF <= 200 h(-1)) for the transfer hydrogenation reaction in comparison to analogous rhodium or iridium complexes. This transfer hydrogenation is characterized by low reversibility under these conditions. Copyright (C) 2011 John Wiley & Sons, Ltd.en_US
dc.description.sponsorshipDicle University [DUAPK 05-FF-27]en_US
dc.description.sponsorshipPartial support from Dicle University (project number: DUAPK 05-FF-27) is gratefully acknowledged.en_US
dc.identifier.citationAydemir, M., Baysal, A. ve Turgut, Y. (2011). Applications of transition metal complexes containing aminophosphine ligand to transfer hydrogenation of ketones. Applied Organometallic Chemistry, 25(4), 270-275.
dc.identifier.doi10.1002/aoc.1753
dc.identifier.endpage275en_US
dc.identifier.issn0268-2605
dc.identifier.issn1099-0739
dc.identifier.issue4en_US
dc.identifier.scopus2-s2.0-79953032764
dc.identifier.scopusqualityQ1
dc.identifier.startpage270en_US
dc.identifier.urihttps://doi.org/10.1002/aoc.1753
dc.identifier.urihttps://hdl.handle.net/11468/13959
dc.identifier.urihttps://onlinelibrary.wiley.com/doi/epdf/10.1002/aoc.1753
dc.identifier.volume25en_US
dc.identifier.wosWOS:000288806300004
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthorAydemir, Murat
dc.institutionauthorBaysal, Akın
dc.institutionauthorTurgut, Yılmaz
dc.language.isoenen_US
dc.publisherWileyen_US
dc.relation.ispartofApplied Organometallic Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectAminophosphineen_US
dc.subjectTransition metalsen_US
dc.subjectTransfer hydrogenationen_US
dc.subjectCatalysisen_US
dc.titleApplications of transition metal complexes containing aminophosphine ligand to transfer hydrogenation of ketonesen_US
dc.titleApplications of transition metal complexes containing aminophosphine ligand to transfer hydrogenation of ketones
dc.typeArticleen_US

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