Synthesis, characterization, electrochemical behaviors and applications in the Suzuki-Miyaura cross-coupling reactions of N2S2O2 thio Schiff base ligand and its Cu(II), Co(III), Ni(II), Pd(II) complexes and their usage in the fabrication of organic-inorganic hybrid devices

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dc.contributor.authorTemel, Hamdi
dc.contributor.authorPasa, Salih
dc.contributor.authorOcak, Yusuf Selim
dc.contributor.authorYilmaz, Ismail
dc.contributor.authorDemir, Serpil
dc.contributor.authorOzdemir, Ismail
dc.date.accessioned2024-04-24T16:18:24Z
dc.date.available2024-04-24T16:18:24Z
dc.date.issued2012
dc.departmentDicle Üniversitesien_US
dc.description.abstractThe thio Schiff base ligand N,N'-bis(o-hydroxy-1-naphtaldehydene)-1,2-bis(o-amino phenilthio)ethane (L) was synthesized by the condensation of o-hydroxy-1-naphthaldehyde and 1,2-bis(2-amino thiophenol)ethane. The reactions of the ligand with different transition metal(II) salts under reflux system condition afforded a series of metal complexes such as Cu(II), Co(III), Ni(II) and Pd(II). Ligand and its complexes were characterized by a combination of elemental analysis, UV-vis spectroscopy, FT-IR, H-1 NMR, MS and TGA/DTA. The electrochemical properties of L and [Cu(L)] were investigated using cyclic voltammetry (CV) in the solutions of dimethyl sulfoxide (DMSO). The catalytic property of thio Schiff base ligand with Suzuki cross-coupling reactions were also determined with different substituted aryl halides in the presence of aryl boronic acid and Pd(AcO)(2) as catalyst. In addition, the fabrication of organic-inorganic hybrid devices using L and its Co(III), Ni(II) and Pd(II) complexes and their electrical properties have been reported. (C) 2011 Elsevier B.V. All rights reserved.en_US
dc.identifier.doi10.1016/j.synthmet.2011.10.018
dc.identifier.endpage2775en_US
dc.identifier.issn0379-6779
dc.identifier.issue23-24en_US
dc.identifier.scopus2-s2.0-84855896178
dc.identifier.scopusqualityQ1
dc.identifier.startpage2765en_US
dc.identifier.urihttps://doi.org/10.1016/j.synthmet.2011.10.018
dc.identifier.urihttps://hdl.handle.net/11468/16074
dc.identifier.volume161en_US
dc.identifier.wosWOS:000300653700048
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoenen_US
dc.publisherElsevier Science Saen_US
dc.relation.ispartofSynthetic Metals
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subject2-Amino Thiophenolen_US
dc.subjectSuzuki Couplingen_US
dc.subjectCyclic Voltammetryen_US
dc.subjectOrganic-Inorganic Heterojunctionen_US
dc.titleSynthesis, characterization, electrochemical behaviors and applications in the Suzuki-Miyaura cross-coupling reactions of N2S2O2 thio Schiff base ligand and its Cu(II), Co(III), Ni(II), Pd(II) complexes and their usage in the fabrication of organic-inorganic hybrid devicesen_US
dc.titleSynthesis, characterization, electrochemical behaviors and applications in the Suzuki-Miyaura cross-coupling reactions of N2S2O2 thio Schiff base ligand and its Cu(II), Co(III), Ni(II), Pd(II) complexes and their usage in the fabrication of organic-inorganic hybrid devices
dc.typeArticleen_US

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