Spectroscopic and extraction studies of new transition metal complexes with N,N'-bis(2-aminothiophenol)-1, 4-bis(2-carboxaldehydephenoxy)butane

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dc.contributor.authorTemel, Hamdi
dc.contributor.authorAlp, Hueseyin
dc.contributor.authorIlhan, Salih
dc.contributor.authorZiyadanogullari, Berrin
dc.date.accessioned2024-04-24T16:24:25Z
dc.date.available2024-04-24T16:24:25Z
dc.date.issued2008
dc.departmentDicle Üniversitesien_US
dc.description.abstractMetal complexes of La(III), Cu(II) and Ni(II) with a thio Schiff base derived from 1,4-bis(2-carboxaldehydephenoxy)butane and 2-aminothiophenol have been synthesized in absolute ethanol and characterized by microanalytical data, magnetic measurements, H-1 NMR, C-13 NMR, UV-visible, IR-spectra, mass spectra and conductance measurements. The extractability of divalent cations was evaluated as a function of relationship between distribution ratios of the metal and pH or ligand concentration. The highest extraction percentage of Cu+2 and Ni+2 were at pH 7.0 and 6.4, respectively. The ligand can effectively be used in solvent extraction of copper(II) and nickel(II) from aqueous phase to organic phase.en_US
dc.identifier.doi10.1080/00958970701502334
dc.identifier.endpage1156en_US
dc.identifier.issn0095-8972
dc.identifier.issn1029-0389
dc.identifier.issue7en_US
dc.identifier.scopus2-s2.0-42449127581
dc.identifier.scopusqualityQ3
dc.identifier.startpage1146en_US
dc.identifier.urihttps://doi.org/10.1080/00958970701502334
dc.identifier.urihttps://hdl.handle.net/11468/16700
dc.identifier.volume61en_US
dc.identifier.wosWOS:000255158200015
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoenen_US
dc.publisherTaylor & Francis Ltden_US
dc.relation.ispartofJournal of Coordination Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectSpectroscopic Studiesen_US
dc.subjectExtraction Studiesen_US
dc.subjectThio Schiff Baseen_US
dc.titleSpectroscopic and extraction studies of new transition metal complexes with N,N'-bis(2-aminothiophenol)-1, 4-bis(2-carboxaldehydephenoxy)butaneen_US
dc.titleSpectroscopic and extraction studies of new transition metal complexes with N,N'-bis(2-aminothiophenol)-1, 4-bis(2-carboxaldehydephenoxy)butane
dc.typeArticleen_US

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