A ruthenium(II) bipyridine complex containing a 4,5-diazafluorene moiety: Synthesis, characterization and its applications in transfer hydrogenation of ketones and dye sensitized solar cells

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dc.contributor.authorBaysal, Akin
dc.contributor.authorAydemir, Murat
dc.contributor.authorDurap, Feyyaz
dc.contributor.authorOzkar, Saim
dc.contributor.authorYildirim, Leyla Tatar
dc.contributor.authorOcak, Yusuf Selim
dc.date.accessioned2024-04-24T16:18:17Z
dc.date.available2024-04-24T16:18:17Z
dc.date.issued2015
dc.departmentDicle Üniversitesien_US
dc.description.abstractThe ruthenium(B) complex [Ru(bpy)(2)L](PF6)(2), where bpy is 2,2'-bipyridine and L is 1,5-dihydro-2-H-cyclopenta[1,2-b:5,4-b']dipyridine-2-one, was synthesized from the reaction of cis-Ru(bpy)(2)Cl-2 center dot 2H(2)O with L, and isolated as the hexafluorophosphate salt. The structure of L was unequivocally elucidated by single-crystal X-ray diffraction analysis. The new ruthenium(II) complex was thoroughly characterized by H-1 and C-13 NMR spectroscopy, along with FTIR, UV-Vis and LC MS/MS Triple Quadrupole Mass spectroscopy and elemental analysis. The catalytic activity of [Ru(bpy)(2)L](PF6)(2) was tested in the transfer hydrogenation of various ketones in 2-propanol as both the solvent and hydrogen donor. The usage of [Ru(bpy)(2)L](PF6)(2) for the formation of a dye sensitized solar cell is also presented. (C) 2015 Elsevier Ltd. All rights reserved.en_US
dc.description.sponsorshipDicle University Research Fund [02-FF-33, DUBAP-14-FF-75]; Turkish Academy of Sciencesen_US
dc.description.sponsorshipPartial support from the Dicle University Research Fund (Project Nos. 02-FF-33, DUBAP-14-FF-75) and the Turkish Academy of Sciences is gratefully acknowledged. The analysis was conducted at Dicle University Science and Technology Application and Research Center (DUBTAM). The authors thank Canan Kazak for the X-ray single crystal data collection.en_US
dc.identifier.doi10.1016/j.poly.2014.12.046
dc.identifier.endpage61en_US
dc.identifier.issn0277-5387
dc.identifier.scopus2-s2.0-84922135720
dc.identifier.scopusqualityQ2
dc.identifier.startpage55en_US
dc.identifier.urihttps://doi.org/10.1016/j.poly.2014.12.046
dc.identifier.urihttps://hdl.handle.net/11468/15962
dc.identifier.volume89en_US
dc.identifier.wosWOS:000351965600008
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoenen_US
dc.publisherPergamon-Elsevier Science Ltden_US
dc.relation.ispartofPolyhedron
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectN Liganden_US
dc.subjectCatalysten_US
dc.subjectTransfer Hydrogenationen_US
dc.subjectDsscen_US
dc.subjectX-Rayen_US
dc.titleA ruthenium(II) bipyridine complex containing a 4,5-diazafluorene moiety: Synthesis, characterization and its applications in transfer hydrogenation of ketones and dye sensitized solar cellsen_US
dc.titleA ruthenium(II) bipyridine complex containing a 4,5-diazafluorene moiety: Synthesis, characterization and its applications in transfer hydrogenation of ketones and dye sensitized solar cells
dc.typeArticleen_US

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