Application of half-sandwich metal-phosphinite compounds to biological activities: Determine the energies of the HOMO and LUMO levels

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dc.contributor.authorMeriç, Nermin
dc.contributor.authorRafikova, Khadichakhan
dc.contributor.authorZazybin, Alexey
dc.contributor.authorGüzel, Remziye
dc.contributor.authorKayan, Cezmi
dc.contributor.authorKarakas, Duygu Elma
dc.contributor.authorDündar, Abdurrahman
dc.contributor.authorAydemir, Murat
dc.date.accessioned2024-04-24T15:59:33Z
dc.date.available2024-04-24T15:59:33Z
dc.date.issued2023
dc.departmentDicle Üniversitesi, Fen-Edebiyat Fakültesi, Kimya Bölümüen_US
dc.description.abstractMononuclear transition metal complexes 1-(furan-2-yl)ethyldiphenyl[dichloro(eta(6)-p-cymene)ruthenium(II)]phosphinite, (2), 1-(furan-2-yl)ethyldiphenyl[dichloro(eta(6)-benzene) ruthenium(II)] phosphinite (3), 1-(furan-2-yl)ethyldipheny[chloro(eta(4)-1,5-cyclooctadiene)rhodium(I)]phosphinite (4), 1-(furan-2-yl)ethyldiphenyl[dichloro (eta(5)pentamethylcyclopentadienyl)iridium (III)] phosphinite (5) were synthesized and characterized by microanalysis, infrared, MS, and NMR spectroscopy. The biological activities of the complexes were also tested. Compounds 2 and 5 were the best complexes at DPPH radical scavenging and reducing power activity at 73.27 % and 0.41 at 200 mu g/mL, respectively. The highest antimicrobial activity exhibited by complex 3 as 14 mm inhibition zone against S. aureus. All of the complexes have cleaved the DNA from the double-strand and exhibited three bands on gel electrophoresis. Moreover, cyclic voltammetry studies of the phosphinite complexes were carried out to determine the energies of the HOMO and LUMO levels as well as to estimate their electrochemical and some electronic properties.en_US
dc.description.sponsorshipScience Committee of the Ministry of Education and Science of the Republic of Kazakhstan; Dicle University; [IRNAP08857516]; [FEN.20.005]en_US
dc.description.sponsorshipAcknowledgements The research is funded by the Science Committee of the Ministry of Education and Science of the Republic of Kazakhstan (Grant No: IRNAP08857516). Partial support of this work by Dicle University (Project number: FEN.20.005) is gratefully acknowledged.en_US
dc.identifier.citationMeriç, N., Rafikova, K., Zazybin, A., Güzel, R., Kayan, C., Karakas, D.E. ve diğerleri (2023). Application of half-sandwich metal-phosphinite compounds to biological activities: Determine the energies of the HOMO and LUMO levels. Environmental Toxicology, 23(6), 672–678.
dc.identifier.doi10.1002/zaac.202200126
dc.identifier.issn0044-2313
dc.identifier.issn1521-3749
dc.identifier.issue2en_US
dc.identifier.scopus2-s2.0-85142272576
dc.identifier.scopusqualityQ3
dc.identifier.urihttps://doi.org/10.1002/zaac.202200126
dc.identifier.urihttps://hdl.handle.net/11468/14140
dc.identifier.urihttps://onlinelibrary.wiley.com/doi/epdf/10.1002/zaac.202200126
dc.identifier.volume649en_US
dc.identifier.wosWOS:000888397300001
dc.identifier.wosqualityQ4
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthorMeriç, Nermin
dc.institutionauthorGüzel, Remziye
dc.institutionauthorKayan, Cezmi
dc.institutionauthorAydemir, Murat
dc.language.isoenen_US
dc.publisherWiley-V C H Verlag Gmbhen_US
dc.relation.ispartofZeitschrift Fur Anorganische Und Allgemeine Chemie
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectPhosphinite liganden_US
dc.subjectTransition metalen_US
dc.subjectBiological studyen_US
dc.subjectElectron transporten_US
dc.titleApplication of half-sandwich metal-phosphinite compounds to biological activities: Determine the energies of the HOMO and LUMO levelsen_US
dc.titleApplication of half-sandwich metal-phosphinite compounds to biological activities: Determine the energies of the HOMO and LUMO levels
dc.typeArticleen_US

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