Rhodium-catalyzed transfer hydrogenation with functionalized bis(phosphino) amine ligands

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dc.contributor.authorAydemir, Murat
dc.contributor.authorMeric, Nermin
dc.contributor.authorKayan, Cezmi
dc.contributor.authorOk, Fatih
dc.contributor.authorBaysal, Akin
dc.date.accessioned2024-04-24T16:14:52Z
dc.date.available2024-04-24T16:14:52Z
dc.date.issued2013
dc.departmentDicle Üniversitesien_US
dc.description.abstractA series of novel cationic mononuclear rhodium( I) complexes with the P-N-P ligands have been prepared starting from the complex [Rh(cod)(2)]BF4. The structural elucidation of the complexes was carried out by elemental analyses, IR and multinuclear NMR spectroscopic data. Furthermore, the complexes were applied to the transfer hydrogenation of ketones in the presence of 2-propanol as the hydrogen source. Catalytic studies showed that all complexes are excellent catalytic precursors for the transfer hydrogenation of aryl alkyl ketones in 0.1 M iso-PrOH solution. Especially, [Rh((Ph2P)(2)N-C6H4-4-CH(CH3)(2))(cod)]BF4 acts as an excellent catalyst giving the corresponding alcohols in excellent conversion up to 99% (TOF <= 1980 h (1)). (C) 2012 Elsevier B.V. All rights reserved.en_US
dc.description.sponsorshipDicle University [DUAPK 05-FF-27]en_US
dc.description.sponsorshipPartial support from Dicle University (Project number: DUAPK 05-FF-27) is gratefully acknowledged.en_US
dc.identifier.doi10.1016/j.ica.2012.12.005
dc.identifier.endpage10en_US
dc.identifier.issn0020-1693
dc.identifier.issn1873-3255
dc.identifier.scopus2-s2.0-84875233707
dc.identifier.scopusqualityQ2
dc.identifier.startpage1en_US
dc.identifier.urihttps://doi.org/10.1016/j.ica.2012.12.005
dc.identifier.urihttps://hdl.handle.net/11468/15457
dc.identifier.volume398en_US
dc.identifier.wosWOS:000316742500001
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoenen_US
dc.publisherElsevier Science Saen_US
dc.relation.ispartofInorganica Chimica Acta
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectBis(Phosphino)Amineen_US
dc.subjectRhodiumen_US
dc.subjectCatalysisen_US
dc.subjectTransfer Hydrogenationen_US
dc.subjectKetoneen_US
dc.titleRhodium-catalyzed transfer hydrogenation with functionalized bis(phosphino) amine ligandsen_US
dc.titleRhodium-catalyzed transfer hydrogenation with functionalized bis(phosphino) amine ligands
dc.typeArticleen_US

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