Ecofriendly synthesis of selenium nanoparticles using agricultural Citrus fortunella waste and decolourization of crystal violet from aqueous solution

dc.contributor.authorSolmaz, Alper
dc.contributor.authorTurna, Talip
dc.contributor.authorBaran, Ayşe
dc.date.accessioned2024-04-24T15:59:22Z
dc.date.available2024-04-24T15:59:22Z
dc.date.issued2024
dc.departmentDicle Üniversitesi, Diyarbakır Teknik Bilimler Meslek Yüksekokulu, Park ve Bahçe Bitkileri Bölümüen_US
dc.description.abstractIn this study, the reuse of Citrus fortunella (CF) plant waste, an agricultural product, was evaluated within the scope of sustainability. In this context, selenium nanoparticles (CF-Se NPs) were synthesized from CF waste extracts and crystal violet (CV) dye was removed. The characteristic structure of the synthesized CF-Se NPs was determined by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray (EDX), Fourier transform infrared spectroscopy (FTIR), UV-vis spectroscopy, and point of zero charge (pH(pzc)). Batch adsorption tests were applied to determine the effect of the synthesized CF-Se NPs on CV removal. Four different kinetic and isotherm models were examined using error analysis functions. While the particle size of CF-Se NPs was determined as 27.58 nm, the pH(pzc) value was calculated as 9.40, the average surface charge distribution was -24.1 mV, and mass losses were 9.03% and 13.42% at 334.99 and 739.21(degrees)C, respectively. The most suitable kinetic and isotherm model for CV removal with CF-Se NPs was determined to be pseudo-second-order with a R-2-value of 0.999 and Freundlich with R-2-value of 0.993, and the q(max )was calculated as 23.55 mgCV/gCF-SeNPs. The effectiveness of CF-Se NPs synthesized from waste in CV removal is a remarkable issue in terms of sustainable production.en_US
dc.description.sponsorshipBatman Universityen_US
dc.description.sponsorshipThe authors would like to thank to M. F & imath;rat Baran, Iskenderun Technical University, Dicle University, and Batman University for their support.en_US
dc.identifier.citationSolmaz, A., Turna, T. ve Baran, A. (2024). Ecofriendly synthesis of selenium nanoparticles using agricultural Citrus fortunella waste and decolourization of crystal violet from aqueous solution. Canadian Journal of Chemical Engineering, 1-17.
dc.identifier.doi10.1002/cjce.25179
dc.identifier.issn0008-4034
dc.identifier.issn1939-019X
dc.identifier.scopus2-s2.0-85182435791
dc.identifier.scopusqualityQ2
dc.identifier.urihttps://doi.org/10.1002/cjce.25179
dc.identifier.urihttps://hdl.handle.net/11468/14017
dc.identifier.wosWOS:001143095100001
dc.identifier.wosqualityN/A
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoenen_US
dc.publisherWileyen_US
dc.relation.ispartofCanadian Journal of Chemical Engineering
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectAdsorptionen_US
dc.subjectAgricultural wasteen_US
dc.subjectCitrus fortunellaen_US
dc.subjectCrystal violeten_US
dc.subjectGreen synthesisen_US
dc.subjectNanoparticleen_US
dc.titleEcofriendly synthesis of selenium nanoparticles using agricultural Citrus fortunella waste and decolourization of crystal violet from aqueous solutionen_US
dc.titleEcofriendly synthesis of selenium nanoparticles using agricultural Citrus fortunella waste and decolourization of crystal violet from aqueous solution
dc.typeArticleen_US

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