Phosphorus-nitrogen compounds: Part 60: Synthesis of hexaminomonoferrocenyl-spiro(N/O)cyclotetraphosphazenes: Spectral and electrochemical properties, tuning of redox feature, and antituberculosis activity

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dc.contributor.authorBinici, Arzu
dc.contributor.authorElmas, Gamze
dc.contributor.authorOkumus, Aytug
dc.contributor.authorGuzel, Remziye
dc.contributor.authorSimsek, Hulya
dc.contributor.authorKilic, Zeynel
dc.date.accessioned2024-04-24T16:24:52Z
dc.date.available2024-04-24T16:24:52Z
dc.date.issued2023
dc.departmentDicle Üniversitesien_US
dc.description.abstractIn the present investigation, the condensation reaction of octachlorocyclotetraphosphazene, N4P4Cl8 (1) (tetramer, OCCP), with sodium 3-(N-ferrocenylmethylamino)-1-propanoxide (L) resulted in the formation of the starting compound hexachloromonoferrocenylspiro(N/O)cyclotetraphosphazene (2). Thereafter, reactions of spiro (2) with excesses of 1-(2-aminoethyl)pyrrolidine, 1-(2-aminoethyl)piperidine and 4-(2-aminoethyl)morpholine in dry THF gave hexaaminomono-ferrocenylspiro(N/O)cyclotetraphosphazenes, 2a, 2b, and 2c, respectively. These new products were prepared for investigation of spectral and electrochemical properties, tuning of redox features, and examination of antituberculosis activities. The structures of 2a-2c were elucidated using elemental analysis, mass spectrometry (ESI-MS), FTIR, HMBC, HSQC, H-1, C-13 {H-1}, and P-31 {H-1} NMR data. The electrochemical behavior of these products containing monoferrocenyl group was investigated. Their use as potential alternative electrolyte redox couples for dye-sensitized solar cells (DSSC) was examined. The findings may inspire solar cell studies to explore the redox mediator behind the working mechanisms of DSSCs. Conversely, the antituberculosis activities of three compounds were examined against Mycobacterium tuberculosis H37Rv. The MIC values of 2a and 2 b were found to be as 30 and 35 mu g/mL, respectively, against the H37Rv reference strain.en_US
dc.description.sponsorshipScientific and Technical Research Council of Turkey [215Z496]; DUBAP [ZGEF.18.013]; Turkish Academy of Sciences (TUBA)en_US
dc.description.sponsorshipThe authors thank the Scientific and Technical Research Council of Turkey (Grant No. 215Z496), and this study is also supported by DUBAP with grand number ZGEF.18.013. Z. K. thanks to Turkish Academy of Sciences (TUBA) for partial support of this work.en_US
dc.identifier.doi10.1080/10426507.2022.2100888
dc.identifier.endpage33en_US
dc.identifier.issn1042-6507
dc.identifier.issn1563-5325
dc.identifier.issue1en_US
dc.identifier.scopus2-s2.0-85134393387
dc.identifier.scopusqualityQ3
dc.identifier.startpage21en_US
dc.identifier.urihttps://doi.org/10.1080/10426507.2022.2100888
dc.identifier.urihttps://hdl.handle.net/11468/16882
dc.identifier.volume198en_US
dc.identifier.wosWOS:000827580500001
dc.identifier.wosqualityQ4
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoenen_US
dc.publisherTaylor & Francis Ltden_US
dc.relation.ispartofPhosphorus Sulfur and Silicon and The Related Elements
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectSpiro-Cyclotetraphosphazenesen_US
dc.subjectSpectroscopyen_US
dc.subjectElectrochemistryen_US
dc.subjectSolar Cell Electrolyteen_US
dc.subjectAntituberculosis Activityen_US
dc.titlePhosphorus-nitrogen compounds: Part 60: Synthesis of hexaminomonoferrocenyl-spiro(N/O)cyclotetraphosphazenes: Spectral and electrochemical properties, tuning of redox feature, and antituberculosis activityen_US
dc.titlePhosphorus-nitrogen compounds: Part 60: Synthesis of hexaminomonoferrocenyl-spiro(N/O)cyclotetraphosphazenes: Spectral and electrochemical properties, tuning of redox feature, and antituberculosis activity
dc.typeArticleen_US

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