Electron paramagnetic resonance and FT-IR spectroscopic studies of DL-2-aminoadipic acid and ammonium acetate powders
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Tarih
2014
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Taylor & Francis Ltd
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
Exposure of powder forms of DL-2-aminoadipic acid and ammonium acetate to gamma radiation results in the formation of free radicals detected by the electron paramagnetic resonance spectroscopy at room temperature. In these compounds, the observed paramagnetic species were attributed to the HOOCCH2CH2CH2CHCOOH and CH2COONH4 radicals, respectively. The g values and the hyperfine coupling constants of the unpaired electron with the environmental protons were determined for these two radicals. In work, the observed paramagnetic species were found to be stable at room temperature for more than two months. Also, these compounds were characterised by FT-IR and UV-VIS. Their thermal stabilities were determined by TGA and DTA measurements. Thermal analyses were shown to be unstable of the HOOCCH2CH2CH2CH(NH2)COOH and CH3COONH4 against thermo-oxidative decomposition.
Açıklama
Anahtar Kelimeler
Ammonium Acetate, Dl-2-Aminoadipic Acid, Ft-Ir, Free Radicals, Epr
Kaynak
Radiation Effects and Defects in Solids
WoS Q Değeri
Q4
Scopus Q Değeri
Q3
Cilt
169
Sayı
3
