Different Hemi-Salen/Salan Ligand Containing Binuclear Boron-Fluoride Complexes: Synthesis, Spectroscopy, Fluorescence Properties, and Catalysis

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dc.contributor.authorKilic, Ahmet
dc.contributor.authorOzbahceci, Orcun
dc.contributor.authorDurgun, Mustafa
dc.contributor.authorAydemir, Murat
dc.date.accessioned2024-04-24T16:24:49Z
dc.date.available2024-04-24T16:24:49Z
dc.date.issued2019
dc.departmentDicle Üniversitesien_US
dc.description.abstractA family of hemi-salen (L1H-L6H) and hemi-salan (L1aH-L2aH) ligands-based N,O-chelated binuclear boron-fluoride [L-n(BF2)(2)] (n = L-1-L-6 or L-1a-L-2a) complexes have been prepared and characterized by a variety of spectroscopic techniques (H-1, C-13 and F-19 NMR, FT-IR, UV-Vis, LC-MS, and fluorescence spectra) and elemental analysis. All of the binuclear boron-fluoride complexes exhibit strong absorption bands due to S-0 -> S-1 transitions and strong fluorescence properties were observed at room temperature in the solution. The binuclear boron complexes containing two naphthyl groups are significantly red-shifted in comparison with the other binuclear boron-fluoride complexes. After the structures are characterized, these hemi-salen and salan ligand-based N, O-chelated binuclear boron-fluoride complexes were utilized to the transfer hydrogenation of the different acetophenone derivatives conversion to 1-phenylethanol derivatives as catalysts.en_US
dc.description.sponsorshipChemistry Department of Harran University, Sanliurfa, Turkeyen_US
dc.description.sponsorshipThis work was supported by the Chemistry Department of Harran University, Sanliurfa, Turkey.en_US
dc.identifier.doi10.1080/10406638.2017.1314973
dc.identifier.endpage265en_US
dc.identifier.issn1040-6638
dc.identifier.issn1563-5333
dc.identifier.issue3en_US
dc.identifier.scopus2-s2.0-85018811724
dc.identifier.scopusqualityQ2
dc.identifier.startpage248en_US
dc.identifier.urihttps://doi.org/10.1080/10406638.2017.1314973
dc.identifier.urihttps://hdl.handle.net/11468/16862
dc.identifier.volume39en_US
dc.identifier.wosWOS:000472107500005
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoenen_US
dc.publisherTaylor & Francis Ltden_US
dc.relation.ispartofPolycyclic Aromatic Compounds
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectBoron Complexesen_US
dc.subjectCatalysisen_US
dc.subjectFluorescenceen_US
dc.subjectSynthesisen_US
dc.subjectSpectroscopyen_US
dc.titleDifferent Hemi-Salen/Salan Ligand Containing Binuclear Boron-Fluoride Complexes: Synthesis, Spectroscopy, Fluorescence Properties, and Catalysisen_US
dc.titleDifferent Hemi-Salen/Salan Ligand Containing Binuclear Boron-Fluoride Complexes: Synthesis, Spectroscopy, Fluorescence Properties, and Catalysis
dc.typeArticleen_US

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