Synthesis and characterization of a new macrocyclic Schiff base derived from 2,6-diaminopyridine and 1,10-bis(2-formylphenyl)-1,4,7,10-tetraoxadecane and its Cu(II), Ni(II), Pb(II), Co(III) and La(III) complexes

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dc.contributor.authorIlhan, Salih
dc.contributor.authorTemel, Hamdi
dc.date.accessioned2024-04-24T16:02:22Z
dc.date.available2024-04-24T16:02:22Z
dc.date.issued2007
dc.departmentDicle Üniversitesien_US
dc.description.abstractA new macrocyclic ligand, 1,3,5-triaza-2,4:7,8:19,20-tribenzo-9,12,15,18-tetraoxacyclounkosa-1,5-diene (L) was synthesized by reaction of 2,6-diaminopyridine and 1,10-bis(2-formylphenyl)-1,4,7,10-tetraoxadecane. Then, its Cu-II, Ni-II, Pb-II, Co-III and La-III complexes were synthesized by the template effect by reaction of 2,6-diaminopyridine and 1,10-bis(2-formylphenyl)-1,4,7,10-tetraoxadecane and Cu(NO3)(2)center dot 3H(2)O, Ni(NO3)(2)center dot 6H(2)O, Pb(NO3)(2), Co(NO3)(2)center dot 6H(2)O, La(NO3)(3)center dot 6H(2)O respectively. The ligand and its metal complexes have been characterized by elemental analysis, IR, H-1 and C-13 NMR, u.v-vis spectra, magnetic susceptibility, conductivity measurements and mass spectra. All complexes are diamagnetic and the Cu-II complex is binuclear. The Co-III complex was oxidized to Co-III.en_US
dc.identifier.doi10.1007/s11243-007-0276-5
dc.identifier.endpage1046en_US
dc.identifier.issn0340-4285
dc.identifier.issn1572-901X
dc.identifier.issue8en_US
dc.identifier.scopus2-s2.0-34748887167
dc.identifier.scopusqualityQ2
dc.identifier.startpage1039en_US
dc.identifier.urihttps://doi.org/10.1007/s11243-007-0276-5
dc.identifier.urihttps://hdl.handle.net/11468/14767
dc.identifier.volume32en_US
dc.identifier.wosWOS:000249666100007
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoenen_US
dc.publisherSpringeren_US
dc.relation.ispartofTransition Metal Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subject[No Keyword]en_US
dc.titleSynthesis and characterization of a new macrocyclic Schiff base derived from 2,6-diaminopyridine and 1,10-bis(2-formylphenyl)-1,4,7,10-tetraoxadecane and its Cu(II), Ni(II), Pb(II), Co(III) and La(III) complexesen_US
dc.titleSynthesis and characterization of a new macrocyclic Schiff base derived from 2,6-diaminopyridine and 1,10-bis(2-formylphenyl)-1,4,7,10-tetraoxadecane and its Cu(II), Ni(II), Pb(II), Co(III) and La(III) complexes
dc.typeArticleen_US

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