Crystal structure of an inclusion complex between chiral monoaza-15-crown-5 and S(-)-1-phenyl-ethyl ammonium percholorate

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dc.contributor.authorÖzbey, S
dc.contributor.authorKaynak, FB
dc.contributor.authorTogrul, M
dc.contributor.authorDemirel, N
dc.contributor.authorHosgören, H
dc.date.accessioned2024-04-24T17:18:02Z
dc.date.available2024-04-24T17:18:02Z
dc.date.issued2003
dc.departmentDicle Üniversitesien_US
dc.description.abstractA new type of inclusion complex, S(-)-1 phenyl ethyl ammonium percholorate complex of R-(-)-2-ethyl-N-benzyl-4,7,10,13-tetraoxa-1-azacyclopentadecane, has been prepared and studied by NMR, IR and single crystal X-ray diffraction techniques. The compound crystallizes in space group P2(1) with cell dimensions a = 10.0000(8), b - 12.281(2), c = 12.331(1)Angstrom, beta = 102.052(7), Z = 2. The host-guest complex is held together by a strong system of hydrogen bonds between the two protons of the ammonium ion as well as the nitrogen and four oxygen atoms of the crown ether The C-O and C-C distances of the 15-membered ring average 1.418 and 1.501 Angstrom while the O-C-C and C-O-C angles average 110.2 and 113.3degrees. The average N-C distance is 1.476 Angstrom.en_US
dc.identifier.doi10.1524/zkri.218.5.381.20734
dc.identifier.endpage384en_US
dc.identifier.issn0044-2968
dc.identifier.issue5en_US
dc.identifier.scopus2-s2.0-0042305041
dc.identifier.scopusqualityN/A
dc.identifier.startpage381en_US
dc.identifier.urihttps://doi.org/10.1524/zkri.218.5.381.20734
dc.identifier.urihttps://hdl.handle.net/11468/18563
dc.identifier.volume218en_US
dc.identifier.wosWOS:000183332100008
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoenen_US
dc.publisherR Oldenbourg Verlagen_US
dc.relation.ispartofZeitschrift Fur Kristallographie
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subject[No Keyword]en_US
dc.titleCrystal structure of an inclusion complex between chiral monoaza-15-crown-5 and S(-)-1-phenyl-ethyl ammonium percholorateen_US
dc.titleCrystal structure of an inclusion complex between chiral monoaza-15-crown-5 and S(-)-1-phenyl-ethyl ammonium percholorate
dc.typeArticleen_US

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