The properties of the new Mn(II)-Co(II)-Mn(II)-type hetero-trinuclear oxime metal complexes with N4 and N4O2 ligands

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dc.contributor.authorKilic, Ahmet
dc.contributor.authorDurap, Feyyaz
dc.contributor.authorBaysal, Akin
dc.contributor.authorDurgun, Mustafa
dc.date.accessioned2024-04-24T16:02:14Z
dc.date.available2024-04-24T16:02:14Z
dc.date.issued2010
dc.departmentDicle Üniversitesien_US
dc.description.abstractThe novel one N-4 and two N4O2 containing hetero-trinuclear oxime metal complexes, [Co(L)(2)(H2O)(2)Mn-2(dafo)(4)](ClO4)(2) (1), [Co(L)(2)(H2O)(2)Mn-2(dafdione)(4)](ClO4)(2) (2), [Co(L)(2)(H2O)(2)Mn-2(dcbpy)(4)](ClO4)(2) (3) and [Co(L)(2)(H2O)(2)Mn-2(phen)(4)](ClO4)(2) (4), (where, L = N,N'-bis(ethyl-4-amino-1-piperidine carboxylate)-glyoxime, dafo = 4,5-diazafluoren-9-one, dafdione = 1H-cyclopenta[1,2-b:5,4-b']dipyridine-2,5-dione, dcbpy = 3,3'-dicarboxy-2,2'-bipyridine and phen = 1,10-phenanthroline) have been synthesized and characterized by UV-Vis, FT-IR spectra, magnetic susceptibility measurements, molar conductivity, X-ray powder techniques, mass spectra and their morphology studied by SEM measurements. The H-bonding (O-H center dot center dot center dot O) in the Mn(II)-Co(II)-Mn(II)-type hetero-trinuclear oxime metal complexes disappears, the Co(II) ion centered into the main oxime core by the coordination of the imino groups while the two Mn(II) ions coordinated to dianionic oxygen donors of the oxime groups and linked to the ligands of dafo, dafdione, dcbpy and phen.en_US
dc.description.sponsorshipHarran University; Dicle University [02-FF-33]en_US
dc.description.sponsorshipThis work has been supported, in part, by the Research Fund of Harran University and Dicle University (Project No. 02-FF-33).en_US
dc.identifier.doi10.1007/s10847-009-9724-5
dc.identifier.endpage429en_US
dc.identifier.issn1388-3127
dc.identifier.issn1573-1111
dc.identifier.issue3-4en_US
dc.identifier.scopus2-s2.0-77952882941
dc.identifier.scopusqualityQ2
dc.identifier.startpage423en_US
dc.identifier.urihttps://doi.org/10.1007/s10847-009-9724-5
dc.identifier.urihttps://hdl.handle.net/11468/14698
dc.identifier.volume67en_US
dc.identifier.wosWOS:000277958600021
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoenen_US
dc.publisherSpringeren_US
dc.relation.ispartofJournal of Inclusion Phenomena and Macrocyclic Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectHetero-Trinuclear Metal Complexesen_US
dc.subjectScanning Electron Microscopy (Sem)en_US
dc.subjectXrd Powder Measurementsen_US
dc.titleThe properties of the new Mn(II)-Co(II)-Mn(II)-type hetero-trinuclear oxime metal complexes with N4 and N4O2 ligandsen_US
dc.titleThe properties of the new Mn(II)-Co(II)-Mn(II)-type hetero-trinuclear oxime metal complexes with N4 and N4O2 ligands
dc.typeArticleen_US

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