Synthesis, spectral studies, and determination of stability constants and thermodynamic parameters for some aromatic diamine transition-metal complexes

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dc.contributor.authorTemel, H
dc.contributor.authorZiyadanogullari, B
dc.contributor.authorAlp, H
dc.contributor.authorAydin, I
dc.contributor.authorAydin, F
dc.contributor.authorIlhan, S
dc.date.accessioned2024-04-24T17:11:55Z
dc.date.available2024-04-24T17:11:55Z
dc.date.issued2006
dc.departmentDicle Üniversitesien_US
dc.description.abstractThe Cu(II) and Zn(II) complexes of aromatic bidentate diamines were prepared and characterized by different analytical and spectral methods. Thermodynamic parameters of complexes of Cu(II) and Zn(II) cations with 1,3-bis(p-aminophenoxy)propane were determined in 60 vol. % DMF-H2O at various ionic strengths (0.07, 0.13, 0.2 M NaNO3) and different temperatures (45, 50, 55, 60 +/- 0.1 degrees C) using a spectrophotometric method. The NaNO3 solution was used to maintain the ionic strength. The stability constants show an inverse relationship with ionic strengths. The thermodynamic parameters of 60 vol. % DMF-H2O (Delta G degrees, Delta H degrees, Delta S degrees) based on these formation constants were determined.en_US
dc.identifier.doi10.1134/S1070328406040099
dc.identifier.endpage286en_US
dc.identifier.issn1070-3284
dc.identifier.issn1608-3318
dc.identifier.issue4en_US
dc.identifier.scopus2-s2.0-33645757072
dc.identifier.scopusqualityQ3
dc.identifier.startpage282en_US
dc.identifier.urihttps://doi.org/10.1134/S1070328406040099
dc.identifier.urihttps://hdl.handle.net/11468/17775
dc.identifier.volume32en_US
dc.identifier.wosWOS:000236860800009
dc.identifier.wosqualityQ4
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoenen_US
dc.publisherPleiades Publishing Incen_US
dc.relation.ispartofRussian Journal of Coordination Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subject[No Keyword]en_US
dc.titleSynthesis, spectral studies, and determination of stability constants and thermodynamic parameters for some aromatic diamine transition-metal complexesen_US
dc.titleSynthesis, spectral studies, and determination of stability constants and thermodynamic parameters for some aromatic diamine transition-metal complexes
dc.typeArticleen_US

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