All-solid-state PVC membrane Ag+-selective electrodes based on diaza-18-crown-6 compounds

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dc.contributor.authorIsildak, I
dc.contributor.authorYolcu, M
dc.contributor.authorIsildak, O
dc.contributor.authorDemirel, N
dc.contributor.authorTopal, G
dc.contributor.authorHosgoren, H
dc.date.accessioned2024-04-24T16:01:56Z
dc.date.available2024-04-24T16:01:56Z
dc.date.issued2004
dc.departmentDicle Üniversitesien_US
dc.description.abstractTwo diaza-crown ether compounds were synthesized and evaluated as Ag+-selective carriers in polyvinylchloride (PVC) membrane electrodes of solid-state type. The all-solid-state PVC membrane electrode based on N,N-Dibenzyl-dibenzo-diaza-18-crown-6 exhibited a super-Nernstian response (75+/-10 mV per decade) over the concentration range of 1x10(-1) to 7x10(-6) M of Ag+ ion and a detection limit of 3x10(-6) M, at a wide range of pH (pH 4-7). The response time of the electrode was fast (less than similar to10s), and it can be used for three months without any significant deviation in potential. The proposed all-solid-state PVC membrane electrodes revealed high selectivity toward Ag+ ion with respect to alkali, alkaline earth, heavy and transition metal ions. A flow-through cell of all-solid-state PVC membrane Ag+-selective electrode based on N,N-Dibenzyl-dibenzo-diaza-18-crown-6 has also been prepared and applied for flow-injection analysis of Ag+ ion in solution.en_US
dc.identifier.doi10.1007/s00604-003-0072-7
dc.identifier.endpage181en_US
dc.identifier.issn0026-3672
dc.identifier.issn1436-5073
dc.identifier.issue1-3en_US
dc.identifier.scopus2-s2.0-20344385497
dc.identifier.scopusqualityQ1
dc.identifier.startpage177en_US
dc.identifier.urihttps://doi.org/10.1007/s00604-003-0072-7
dc.identifier.urihttps://hdl.handle.net/11468/14517
dc.identifier.volume144en_US
dc.identifier.wosWOS:000188300100026
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoenen_US
dc.publisherSpringer Wienen_US
dc.relation.ispartofMicrochimica Acta
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectDiaza-Crown Ethersen_US
dc.subjectAll-Solid-Stateen_US
dc.subjectPvc Membraneen_US
dc.subjectSilver-Selective Electrodesen_US
dc.subjectFiaen_US
dc.titleAll-solid-state PVC membrane Ag+-selective electrodes based on diaza-18-crown-6 compoundsen_US
dc.titleAll-solid-state PVC membrane Ag+-selective electrodes based on diaza-18-crown-6 compounds
dc.typeArticleen_US

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