Synthesis, Characterization, Crystal and Molecular Structure of 1,5-Dihydro-2H-cyclopenta[1,2-b:5,4-b′]dipyridin-2-imine

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dc.contributor.authorBaysal, Akın
dc.contributor.authorDurap, Feyyaz
dc.contributor.authorGümgüm, Bahattin
dc.contributor.authorYıldırım, Leyla T.
dc.contributor.authorÜlkü, Dinçer
dc.contributor.authorBoğa, Ayşe Dilek
dc.contributor.authorÖzkar, Saim
dc.contributor.orcid0000-0001-7294-6792
dc.contributor.orcid0000-0003-0899-1948
dc.date.accessioned2024-04-24T15:59:24Z
dc.date.available2024-04-24T15:59:24Z
dc.date.issued2007
dc.departmentDicle Üniversitesi, Fen Fakültesi, Kimya Bölümüen_US
dc.description.abstractThe reaction of 1,5-diliydro-2H-cyclopenta[1,2-b:5,4-b'ldipyridin-2-one (3) with an alkylamine (butvlamine, hexylamine or ethylenediamine) yields, quite unexpectedly and in the absence of catalyst, the novel compound 1,5-dihydro-2H-cyclopentafl,2-b:5.4-b']dipyridin-2-imine (4) as the sole, analytically pure, solid product, which was fully characterized. The structure of 4 was unequivocally solved by single-crystal X-ray-diffraction analysis. The compound crystallizes in a monoclinic cell (space group P 2(1/c)). with two molecules in the asymmetric unit. held together by intermolecular H-bonds. Compound 4 could be interesting as a bi- or even tridentate ligand, and exhibits a strong fluorescence upon excitation at 310 nm. A mechanism, based on the observed C-N bond cleavage, is proposed.en_US
dc.identifier.citationBaysal, A., Durap, F., Gümgüm, B., Yıldırım, L. T., Ülkü, D., Boğa, A. D. ve diğerleri. (2007). Synthesis, characterization, crystal and molecular structure of 1,5-Dihydro-2H-cyclopenta[1,2-b:5,4-b′]dipyridin-2-imine, Helvetica Chimica Acta, 90(6), 1211-1217.
dc.identifier.doi10.1002/hlca.200790120
dc.identifier.endpage1217en_US
dc.identifier.issn0018-019X
dc.identifier.issue6en_US
dc.identifier.scopus2-s2.0-34447327284
dc.identifier.scopusqualityQ3
dc.identifier.startpage1211en_US
dc.identifier.urihttps://doi.org/10.1002/hlca.200790120
dc.identifier.urihttps://hdl.handle.net/11468/14041
dc.identifier.urihttps://onlinelibrary.wiley.com/doi/epdf/10.1002/hlca.200790120
dc.identifier.volume90en_US
dc.identifier.wosWOS:000247690600016
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthorBaysal, Akın
dc.institutionauthorDurap, Feyyaz
dc.institutionauthorGümgüm, Bahattin
dc.language.isoenen_US
dc.publisherWiley-V C H Verlag Gmbhen_US
dc.relation.ispartofHelvetica Chimica Acta
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subject[No Keyword]en_US
dc.titleSynthesis, Characterization, Crystal and Molecular Structure of 1,5-Dihydro-2H-cyclopenta[1,2-b:5,4-b′]dipyridin-2-imineen_US
dc.titleSynthesis, Characterization, Crystal and Molecular Structure of 1,5-Dihydro-2H-cyclopenta[1,2-b:5,4-b?]dipyridin-2-imine
dc.typeArticleen_US

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