Synthesis, Characterization, DFT Studies, and Photodiode Application of Azo-azomethine-Based Ligand and Its Transition-Metal Complexes

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dc.contributor.authorTombak, Ahmet
dc.contributor.authorImer, Arife Gencer
dc.contributor.authorSyan, Ranjdar Hamad Basha
dc.contributor.authorGulcan, Mehmet
dc.contributor.authorGumus, Selcuk
dc.contributor.authorOcak, Yusuf Selim
dc.date.accessioned2024-04-24T16:02:30Z
dc.date.available2024-04-24T16:02:30Z
dc.date.issued2018
dc.departmentDicle Üniversitesien_US
dc.description.abstractAn azo-azomethine-based ligand (H2L) and its transition-metal complexes were prepared, and the electronic structure of the synthesized compounds obtained computationally using density functional theory at B3LYP/6-31G (d,p) level. Furthermore, organic-inorganic heterojunctions were fabricated by forming thin films of complexes of H2L and Co(II), Ni(II), and Pd(II) metal on n-Si substrate. The fundamental electrical parameters of the rectifying heterojunctions were identified based on current-voltage data obtained in the dark at room temperature. The photosensing properties of the devices were investigated under illumination at various intensities from 40 mW/cm(2) to 100 mW/cm(2). The results showed that the photoelectrical characteristics of the devices could be modified by the thin film of metal complex, with the best photosensing properties being obtained for the heterojunction based on compound 1.en_US
dc.description.sponsorshipVan Yuzuncu Yil University [FHD 2018 7160, FYL 2018 7302]en_US
dc.description.sponsorshipPartial support of this work by Van Yuzuncu Yil University (Project IDs: FHD 2018 7160, FYL 2018 7302) is gratefully acknowledged. R.H. Basha Syan and M. Gulcan synthesized compounds 1 to 4 according to the references, while S. Gumus focused on the computational study. A. Gencer Imer, A. Tombak, and Y.S. Ocak fabricated the photodiodes using these compounds as an interlayer, and analyzed their electrical and photoelectrical properties.en_US
dc.identifier.doi10.1007/s11664-018-6657-z
dc.identifier.endpage7250en_US
dc.identifier.issn0361-5235
dc.identifier.issn1543-186X
dc.identifier.issue12en_US
dc.identifier.scopus2-s2.0-85053708834
dc.identifier.scopusqualityQ2
dc.identifier.startpage7240en_US
dc.identifier.urihttps://doi.org/10.1007/s11664-018-6657-z
dc.identifier.urihttps://hdl.handle.net/11468/14819
dc.identifier.volume47en_US
dc.identifier.wosWOS:000448979100033
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoenen_US
dc.publisherSpringeren_US
dc.relation.ispartofJournal of Electronic Materials
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectAzo-Azomethineen_US
dc.subjectTransition-Metal Complexen_US
dc.subjectDft Studyen_US
dc.subjectPhotodiodeen_US
dc.titleSynthesis, Characterization, DFT Studies, and Photodiode Application of Azo-azomethine-Based Ligand and Its Transition-Metal Complexesen_US
dc.titleSynthesis, Characterization, DFT Studies, and Photodiode Application of Azo-azomethine-Based Ligand and Its Transition-Metal Complexes
dc.typeArticleen_US

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