Catechol-type ligand containing new modular design dioxaborinane compounds: Use in the transfer hydrogenation of various ketones

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dc.contributor.authorKilic, Ahmet
dc.contributor.authorKaya, Ibrahim Halil
dc.contributor.authorOzaslan, Ismail
dc.contributor.authorAydemir, Murat
dc.contributor.authorDurap, Feyyaz
dc.date.accessioned2024-04-24T16:11:00Z
dc.date.available2024-04-24T16:11:00Z
dc.date.issued2018
dc.departmentDicle Üniversitesien_US
dc.description.abstractA novel class of tricoordinate dioxaborinane compounds, which have the general formula [B-1(L1-5)] and [B-2(L1-5)], were designed and synthesized by the corresponding catechol-type ligands (L-1-L-5) at ambient temperature. All the new compounds were fully characterized by NMR (H-1, C-13, and B-11), FT-IR, UV-vis, LC-MS spectroscopy, and melting point analysis and microanalysis. The dioxaborinane [B-1(L1-5)] and [B-2(L1-5)] compounds were investigated as catalyst for the transfer hydrogenation of various ketones under suitable conditions. Particularly, it was proved that the ferrocene-based dioxaborinane [B-1(L1-5)] molecules can afford an efficient catalytic conversion compared to corresponding 3,5-bis(trifluoromethyl)phenyl-based [B-2(L1-5)] dioxaborinanes in transfer hydrogenation catalytic studies.en_US
dc.description.sponsorshipTUBITAK [113Z297]; Harran University; Dicle University [FEN.17.019]en_US
dc.description.sponsorshipSupport from TUBITAK (Project number: 113Z297) is gratefully acknowledged. In addition, partial supports of this work by Harran University and Dicle University (Project number: FEN.17.019) are gratefully acknowledged.en_US
dc.identifier.doi10.1016/j.catcom.2018.03.023
dc.identifier.endpage46en_US
dc.identifier.issn1566-7367
dc.identifier.issn1873-3905
dc.identifier.scopus2-s2.0-85044934239
dc.identifier.scopusqualityQ2
dc.identifier.startpage42en_US
dc.identifier.urihttps://doi.org/10.1016/j.catcom.2018.03.023
dc.identifier.urihttps://hdl.handle.net/11468/15224
dc.identifier.volume111en_US
dc.identifier.wosWOS:000433266800009
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoenen_US
dc.publisherElsevier Science Bven_US
dc.relation.ispartofCatalysis Communications
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectCatechol-Type Ligandsen_US
dc.subjectDioxaborinanesen_US
dc.subjectSpectroscopyen_US
dc.subjectTransfer Hydrogenationen_US
dc.subjectKetonesen_US
dc.titleCatechol-type ligand containing new modular design dioxaborinane compounds: Use in the transfer hydrogenation of various ketonesen_US
dc.titleCatechol-type ligand containing new modular design dioxaborinane compounds: Use in the transfer hydrogenation of various ketones
dc.typeArticleen_US

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