Synthesis of new aminophosphine complexes and their catalytic activities in C-C coupling reactions

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dc.contributor.authorBiricik, Nermin
dc.contributor.authorDurap, Feyyaz
dc.contributor.authorKayan, Cezmi
dc.contributor.authorGuemguema, Bahattin
dc.contributor.authorGuerbuez, Nevin
dc.contributor.authorOezdemir, Ismail
dc.contributor.authorAng, Wee Han
dc.date.accessioned2024-04-24T16:15:14Z
dc.date.available2024-04-24T16:15:14Z
dc.date.issued2008
dc.departmentDicle Üniversitesien_US
dc.description.abstractTwo new aminophosphines, benzyl-N(Ph2P)(2) and 2-picolyl-N(Ph2P)(2), have been synthesized. Oxidation of the aminophosphines with either hydrogen peroxide, elemental sulfur and selenium gave the corresponding oxides, sulfides and selenides benzyl-N(Ph2P=E)(2) and 2-picolyl-N(Ph2P=E)(2), where E = O, S, or Se. Complexes [benzyl-N(Ph2P)(2)]MCl2 and [2-picolyl-N(Ph2P)(2)]MCl2, where M = Pd, Pt, were obtained by the reaction of the aminophosphines with MCl2(cod). The new compounds were characterised by NMR, IR spectroscopy and microanalysis. Furthermore, representative solid-state structures of the palladium and platinum complexes were determined using single crystal X-ray diffraction analysis. The palladium complexes were further investigated as potential catalysts in C-C coupling reactions. (c) 2008 Elsevier B. V. All rights reserved.en_US
dc.identifier.doi10.1016/j.jorganchem.2008.05.010
dc.identifier.endpage2699en_US
dc.identifier.issn0022-328X
dc.identifier.issn1872-8561
dc.identifier.issue16en_US
dc.identifier.scopus2-s2.0-47049085410
dc.identifier.scopusqualityQ2
dc.identifier.startpage2693en_US
dc.identifier.urihttps://doi.org/10.1016/j.jorganchem.2008.05.010
dc.identifier.urihttps://hdl.handle.net/11468/15713
dc.identifier.volume693en_US
dc.identifier.wosWOS:000257656100008
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoenen_US
dc.publisherElsevier Science Saen_US
dc.relation.ispartofJournal of Organometallic Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectAminophosphineen_US
dc.subjectSynthesisen_US
dc.subjectOxidationen_US
dc.subjectX-Ray Structuresen_US
dc.subjectCatalysisen_US
dc.titleSynthesis of new aminophosphine complexes and their catalytic activities in C-C coupling reactionsen_US
dc.titleSynthesis of new aminophosphine complexes and their catalytic activities in C-C coupling reactions
dc.typeArticleen_US

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