Photochemical reactions of M(CO)5THF (M = Cr, Mo, W) with thio Schiff bases

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dc.contributor.authorKarahan, Senem
dc.contributor.authorKose, Pelin
dc.contributor.authorSubasi, Elif
dc.contributor.authorAlp, Huseyin
dc.contributor.authorTemel, Hamdi
dc.date.accessioned2024-04-24T16:02:23Z
dc.date.available2024-04-24T16:02:23Z
dc.date.issued2008
dc.departmentDicle Üniversitesien_US
dc.description.abstractThe hitherto unknown complexes, [M-2(CO)(6)-(mu-CO)(mu-L)], [M = Cr; 1, Mo; 2, W; 3] and [M-2(CO)(6)-(mu-CO)(mu-L ')], [M = Cr; 4, Mo; 5, W; 6] have been synthesized by the photochemical reactions of photogenerated intermediate, M(CO)(5)THF (M = Cr, Mo, W) with thio Schiff base ligands, N,N '-bis(2-aminothiophenol)-1,4-bis(2-carboxaldehydephenoxy)butane (H2L) and N,N '-bis(2-aminothiophenol)- 1,7-bis(2-formylphenyl)-1,4,7-trioxaheptane (H2L '). The complexes have been characterized by elemental analysis, LC-mass spectrometry, magnetic studies, FT-IR and H-1 NMR spectroscopy. The spectroscopic studies show that H2L and H2L ' ligands are converted to benzothiazole derivatives, L and L ' after UV irradiation and coordinated to the central metal as bridging ligands via the central azomethine nitrogen and sulphur atoms in 1-6.en_US
dc.description.sponsorshipResearch Foundation of Dokuz Eylul; Dicle University; Dokuz Eylul University [05.KB.FEN.019]en_US
dc.description.sponsorshipWe thank the Research Foundation of Dokuz Eylul and Dicle University for funds. We thank TUBITAK for allocation of time at the Mass Spectra and Elemental Analyses. We thank Ege University for obtaining 1H NMR spectra. This work was supported by Dokuz Eylul University, Project: 05.KB.FEN.019.en_US
dc.identifier.doi10.1007/s11243-008-9121-8
dc.identifier.endpage854en_US
dc.identifier.issn0340-4285
dc.identifier.issn1572-901X
dc.identifier.issue7en_US
dc.identifier.scopus2-s2.0-50949087616
dc.identifier.scopusqualityQ2
dc.identifier.startpage849en_US
dc.identifier.urihttps://doi.org/10.1007/s11243-008-9121-8
dc.identifier.urihttps://hdl.handle.net/11468/14768
dc.identifier.volume33en_US
dc.identifier.wosWOS:000259611700008
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoenen_US
dc.publisherSpringeren_US
dc.relation.ispartofTransition Metal Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subject[No Keyword]en_US
dc.titlePhotochemical reactions of M(CO)5THF (M = Cr, Mo, W) with thio Schiff basesen_US
dc.titlePhotochemical reactions of M(CO)5THF (M = Cr, Mo, W) with thio Schiff bases
dc.typeArticleen_US

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