Synthesis, Crystallographic and Spectral Studies of 3-(4-(Phenylamino) Phenylamino)Cyclohex-2-Enone

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dc.contributor.authorTimur, Mahir
dc.contributor.authorKavak, Guelten
dc.contributor.authorSenoz, Hulya
dc.contributor.authorIde, Semra
dc.contributor.authorTunoglu, Nazan
dc.date.accessioned2024-04-24T16:02:14Z
dc.date.available2024-04-24T16:02:14Z
dc.date.issued2010
dc.departmentDicle Üniversitesien_US
dc.description.abstractThe title compound, 3-(4-(phenylamino)phenylamino)cyclohex-2-enone, beta- enaminone of 1,3-cyclohexanedione and p-amino diphenylamine (C18H18N2O) was prepared and characterized by H-1-NMR, C-13-NMR, Elemental analysis and IR spectroscopy as well as single crystal X-ray diffraction. These results indicate the predominance of the keto-enol tautomerism. Molecular conformation around the central disubstituted benzene ring is affected by the tautomerism and two steric effects between side molecular groups and mono substituted benzene ring. Electron delocalizations due to these effects have been observed in the molecular structure, the structure being stabilized by some intermolecular hydrogen bonds.en_US
dc.description.sponsorshipHacettepe University [01.02.602.002, 05A601009]en_US
dc.description.sponsorshipThis work was supported financially by Hacettepe University (Research Center Office/Projects No: 01.02.602.002 and 05A601009).en_US
dc.identifier.doi10.1007/s10870-009-9664-3
dc.identifier.endpage380en_US
dc.identifier.issn1074-1542
dc.identifier.issn1572-8854
dc.identifier.issue4en_US
dc.identifier.scopus2-s2.0-77950865645
dc.identifier.scopusqualityQ3
dc.identifier.startpage376en_US
dc.identifier.urihttps://doi.org/10.1007/s10870-009-9664-3
dc.identifier.urihttps://hdl.handle.net/11468/14706
dc.identifier.volume40en_US
dc.identifier.wosWOS:000275538900016
dc.identifier.wosqualityQ4
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoenen_US
dc.publisherSpringer/Plenum Publishersen_US
dc.relation.ispartofJournal of Chemical Crystallography
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectSchiff Baseen_US
dc.subjectBeta-Enaminoneen_US
dc.subjectCyclohexanedioneen_US
dc.subjectCrystal Structureen_US
dc.subjectSpectroscopic Studiesen_US
dc.subjectTautomerismen_US
dc.titleSynthesis, Crystallographic and Spectral Studies of 3-(4-(Phenylamino) Phenylamino)Cyclohex-2-Enoneen_US
dc.titleSynthesis, Crystallographic and Spectral Studies of 3-(4-(Phenylamino) Phenylamino)Cyclohex-2-Enone
dc.typeArticleen_US

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