Spectroscopic and electrochemical studies of transition metal complexes with N,N?-bis(2-aminothiophenol)-1,7-bis(2-formylphenyl)-1,4,7-trioxaheptane and structure effects on extractability of ligand towards some divalent cations

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dc.contributor.authorTemel, Hamdi
dc.contributor.authorAlp, Hueseyin
dc.contributor.authorIlhan, Salih
dc.contributor.authorZiyadanogullari, Berrin
dc.contributor.authorYilmaz, Ismail
dc.date.accessioned2024-04-24T16:01:57Z
dc.date.available2024-04-24T16:01:57Z
dc.date.issued2007
dc.departmentDicle Üniversitesien_US
dc.description.abstractLa(III), Cu(II), Ni(II), and Zn(II) metal complexes with a novel quadridentate Schiff base derived from 1,7-bis(2-formylphenyl)-1,4,7-trioxaheptane and 2-aminothiophenol were synthesized and characterized by microanalytical data, elemental analysis, magnetic measurements, H-1 NMR, C-13 NMR, UV-Vis, IR, mass spectra, cyclic voltammetric and conductance measurements. The extractability of divalent cations was evaluated as a function of relationship between distribution ratio of the metal and pH or ligand concentration. The highest extraction percentage of Cu2+ and Ni2+ showed pH 7.0 and 6.4. It was concluded that the ligand can effectively be used in solvent extraction of copper(II) and nickel(II) from the aqueous phase to the organic phase.en_US
dc.identifier.doi10.1007/s00706-007-0713-3
dc.identifier.endpage1209en_US
dc.identifier.issn0026-9247
dc.identifier.issn1434-4475
dc.identifier.issue12en_US
dc.identifier.scopus2-s2.0-36749079826
dc.identifier.scopusqualityQ2
dc.identifier.startpage1199en_US
dc.identifier.urihttps://doi.org/10.1007/s00706-007-0713-3
dc.identifier.urihttps://hdl.handle.net/11468/14528
dc.identifier.volume138en_US
dc.identifier.wosWOS:000251238400001
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoenen_US
dc.publisherSpringer Wienen_US
dc.relation.ispartofMonatshefte Fur Chemie
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectThio Schiff Baseen_US
dc.subjectTransition Metal Complexesen_US
dc.subjectExtractionen_US
dc.subjectElectrochemical Studiesen_US
dc.titleSpectroscopic and electrochemical studies of transition metal complexes with N,N?-bis(2-aminothiophenol)-1,7-bis(2-formylphenyl)-1,4,7-trioxaheptane and structure effects on extractability of ligand towards some divalent cationsen_US
dc.titleSpectroscopic and electrochemical studies of transition metal complexes with N,N?-bis(2-aminothiophenol)-1,7-bis(2-formylphenyl)-1,4,7-trioxaheptane and structure effects on extractability of ligand towards some divalent cations
dc.typeArticleen_US

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