Synthesis and single crystal structure analysis of three novel benzoylthiourea derivatives

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dc.contributor.authorKavak, Guelten
dc.contributor.authorOzbey, Sueheyla
dc.contributor.authorBinzet, Guen
dc.contributor.authorKulcu, Nevzat
dc.date.accessioned2024-04-24T17:21:03Z
dc.date.available2024-04-24T17:21:03Z
dc.date.issued2009
dc.departmentDicle Üniversitesien_US
dc.description.abstractN,N-dimethyl-N'-(2-methylbenzoyl)thiourea, C11H14N2SO (HL1), N,N-dibutyl-N'-(2-methylbenzoyl) thiourea, C17H26N2SO (HL2), and N,N-dihexyl-N'-(2-methylbenzoyl) thiourea, C21H34N2SO (HL3) were synthesized and characterized by elemental analysis, spectroscopic methods (FT-IR, NMR), and single crystal X-ray diffraction. Compound HL1 crystallizes in the monoclinic system, space group P2(1)/c, Z = 4. Compound HL3 also crystallizes in the monoclinic system, space group P2(1)/n, Z = 8 with 2 independent molecules in the asymmetric unit. Compound HL2 crystallizes in the orthorhombic system, space group Penn, Z = 8. In all compounds, molecules form dimers through the strong intermolecular N-H center dot center dot center dot S hydrogen bonds. Moreover, there are different types of intra-and inter-molecular interactions in the crystal structures, and so the molecules of the 3 compounds also pack differently.en_US
dc.description.sponsorshipMersin University Research Fund [BAP-FEF KB (NK) 2006-3]; Hacettepe University Research Fund [03 02 602 001]en_US
dc.description.sponsorshipThe synthesis section of this study is a part of Gun BINZET's PhD thesis and was supported by Mersin University Research Fund (Project No: BAP-FEF KB (NK) 2006-3).; Hacettepe University Research Fund is gratefully acknowledged for its financial support (Project number: 03 02 602 001).en_US
dc.identifier.doi10.3906/kim-0901-1
dc.identifier.endpage868en_US
dc.identifier.issn1300-0527
dc.identifier.issue6en_US
dc.identifier.startpage857en_US
dc.identifier.trdizinid94252
dc.identifier.urihttps://doi.org/10.3906/kim-0901-1
dc.identifier.urihttps://search.trdizin.gov.tr/yayin/detay/94252
dc.identifier.urihttps://hdl.handle.net/11468/19351
dc.identifier.volume33en_US
dc.identifier.wosWOS:000272357300013
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakTR-Dizin
dc.language.isoenen_US
dc.publisherTubitak Scientific & Technological Research Council Turkeyen_US
dc.relation.ispartofTurkish Journal of Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectThiourea Derivativesen_US
dc.subjectBenzoylthioureasen_US
dc.subjectSingle Crystal X-Ray Structuresen_US
dc.titleSynthesis and single crystal structure analysis of three novel benzoylthiourea derivativesen_US
dc.titleSynthesis and single crystal structure analysis of three novel benzoylthiourea derivatives
dc.typeArticleen_US

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