Synthesis and spectral studies of macrocyclic Pb(II), Zn(II), Cd(II) and La(III) complexes derived from 1,4-bis(3-aminopropoxy)butane with metal nitrate and salicylaldehyde derivatives

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dc.contributor.authorIlan, Salih
dc.contributor.authorTemel, Hamdi
dc.contributor.authorPasa, Salih
dc.date.accessioned2024-04-24T16:11:00Z
dc.date.available2024-04-24T16:11:00Z
dc.date.issued2009
dc.departmentDicle Üniversitesien_US
dc.description.abstractEight new macrocyclic complexes were synthesized by template reaction of 1,4-bis(3-aminopropoxy)butane with metal nitrate and 1,3-bis(2-formylphenyl)propane or 1,4-bis(2-formylphenyl)butane and their structures were proposed on the basis of elemental analysis, FTIR, UV-vis, molar conductivity measurements, H-1 NMR and mass spectra. The metals to ligand molar ratios of the complexes were found to be 1:1. The complexes are 1:2 electrolytes for Pb(II), Zn(II) and Cd(II) complexes and 1:3 electrolytes for La(III) as shown by their molar conductivities (Lambda(m)) in DMSO at 10(-3) mol L-1. Due to the existence of free ions in these complexes, such complexes are electrically conductive. The configurations of La(III) and Pb(II) were proposed to probably octahedral and Zn(II) and Cd(II) complexes were proposed to probably tetrahedral. (C) 2008 Salih Ilhan. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.en_US
dc.identifier.doi10.1016/j.cclet.2008.12.008
dc.identifier.endpage343en_US
dc.identifier.issn1001-8417
dc.identifier.issn1878-5964
dc.identifier.issue3en_US
dc.identifier.scopus2-s2.0-59349112340
dc.identifier.scopusqualityQ1
dc.identifier.startpage339en_US
dc.identifier.urihttps://doi.org/10.1016/j.cclet.2008.12.008
dc.identifier.urihttps://hdl.handle.net/11468/15228
dc.identifier.volume20en_US
dc.identifier.wosWOS:000264377000024
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoenen_US
dc.publisherElsevier Science Incen_US
dc.relation.ispartofChinese Chemical Letters
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectMacrocyclic Schiff Baseen_US
dc.subjectMacrocyclic Complexesen_US
dc.subjectSalicylaldehyde Derivativesen_US
dc.subject1,4-Bis(3-Aminopropoxy)Butaneen_US
dc.titleSynthesis and spectral studies of macrocyclic Pb(II), Zn(II), Cd(II) and La(III) complexes derived from 1,4-bis(3-aminopropoxy)butane with metal nitrate and salicylaldehyde derivativesen_US
dc.titleSynthesis and spectral studies of macrocyclic Pb(II), Zn(II), Cd(II) and La(III) complexes derived from 1,4-bis(3-aminopropoxy)butane with metal nitrate and salicylaldehyde derivatives
dc.typeArticleen_US

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