The synthesis, characterization and conductance studies of new Cu(II), Ni(II) and Zn(II) complexes with the Schiff base derived from 1,2-bis-(o-aminophenoxy)ethane and salicylaldehyde

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dc.contributor.authorTemel, H
dc.contributor.authorÇakir, Ü
dc.contributor.authorUgras, HI
dc.contributor.authorSekerci, M
dc.date.accessioned2024-04-24T16:24:24Z
dc.date.available2024-04-24T16:24:24Z
dc.date.issued2003
dc.departmentDicle Üniversitesien_US
dc.description.abstractCu(II), Ni(II) and Zn(II) complexes with the Schiff base derived from 1,2-bis-(omicron-aminophenoxy)ethane with salicylaidehyde have been prepared. The complexes have been characterized by elemental analysis, magnetic measurements, H-1 NMR, C NMR, UV, visible and IR spectra as well as conductance measurements. The ligand is coordinated to the central metal as a tetradentate ONNO ligand. The four bonding sites are the central azomethine nitrogen and aldehydic OH groups. The ligand was used for complexation studies. Stability constants were measured by a conductometric method. Furthermore, the stability constants for complexation between ZnCl2 and Cu(NO3)(2) salts and N,N'-bis(salicylidene)-1,2-bis-(omicron-aminophenoxy)-ethane (H2L) in 80% dioxane/water and pure methanol were determined from conductance measurements. The magnitudes of these ion association constants are related to the nature of the solvation of the cation and the complexed cation. The mobilities of the complexes are also dependent, in part, upon solvation effects.en_US
dc.identifier.doi10.1080/0095897031000135324
dc.identifier.endpage951en_US
dc.identifier.issn0095-8972
dc.identifier.issn1029-0389
dc.identifier.issue11en_US
dc.identifier.scopus2-s2.0-0141537074
dc.identifier.scopusqualityQ3
dc.identifier.startpage943en_US
dc.identifier.urihttps://doi.org/10.1080/0095897031000135324
dc.identifier.urihttps://hdl.handle.net/11468/16692
dc.identifier.volume56en_US
dc.identifier.wosWOS:000185480500003
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoenen_US
dc.publisherTaylor & Francis Ltden_US
dc.relation.ispartofJournal of Coordination Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectSchiff Baseen_US
dc.subjectCu(Ii)en_US
dc.subjectNi(Ii) And Zn(Ii) Complexesen_US
dc.subjectStability Constantsen_US
dc.titleThe synthesis, characterization and conductance studies of new Cu(II), Ni(II) and Zn(II) complexes with the Schiff base derived from 1,2-bis-(o-aminophenoxy)ethane and salicylaldehydeen_US
dc.titleThe synthesis, characterization and conductance studies of new Cu(II), Ni(II) and Zn(II) complexes with the Schiff base derived from 1,2-bis-(o-aminophenoxy)ethane and salicylaldehyde
dc.typeArticleen_US

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