Electron paramagnetic resonance study of gamma induced free radicals in single crystal of 1-[2-(1-ethoxy-carbonyl-3-phenylpropylamino)propionyl]octahydrocylo-penta[b]pyrrole-2-carboxylic acid

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dc.contributor.authorOsmanoglu, Y. Emre
dc.date.accessioned2024-04-24T16:15:37Z
dc.date.available2024-04-24T16:15:37Z
dc.date.issued2020
dc.departmentDicle Üniversitesien_US
dc.description.abstractThe aim of this study was to investigate the structure of the radicals produced by gamma irradiation on single crystals of 1-[2-(1-ethoxy-carbonyl-3-phenyl propyl amino) propionyl]octahydrocylo-penta[b] pyrrole-2-carboxylic acid (C23H32N2O5) by using electron paramagnetic resonance spectroscopy technique. The radiation-induced free radical of single crystals was studied at the temperatures between 120 and 300 K and it has been found that gamma-irradiation produced the C gamma H2C beta H2CNH(COOC2H5) radicals. The hyperfine coupling constants and the g value of the free radical was reported as A(C beta H2C gamma H)(2) = 1.37 mT, a(N) = 1.10 mT and g = 2.0061. The free radical formed in compound was observed to be stable at 300 K during two months of gamma-irradiation. The results were observed as being in good conformity with the existing literature. (C) 2019 Elsevier B.V. All rights reserved.en_US
dc.identifier.doi10.1016/j.molstruc.2019.127455
dc.identifier.issn0022-2860
dc.identifier.issn1872-8014
dc.identifier.scopus2-s2.0-85075973746
dc.identifier.scopusqualityQ1
dc.identifier.urihttps://doi.org/10.1016/j.molstruc.2019.127455
dc.identifier.urihttps://hdl.handle.net/11468/15871
dc.identifier.volume1204en_US
dc.identifier.wosWOS:000508216300026
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoenen_US
dc.publisherElsevieren_US
dc.relation.ispartofJournal of Molecular Structure
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectElectron Paramagnetic Resonanceen_US
dc.subjectGamma-Irradiationen_US
dc.subjectFree Radicalsen_US
dc.subjectDrugsen_US
dc.titleElectron paramagnetic resonance study of gamma induced free radicals in single crystal of 1-[2-(1-ethoxy-carbonyl-3-phenylpropylamino)propionyl]octahydrocylo-penta[b]pyrrole-2-carboxylic aciden_US
dc.titleElectron paramagnetic resonance study of gamma induced free radicals in single crystal of 1-[2-(1-ethoxy-carbonyl-3-phenylpropylamino)propionyl]octahydrocylo-penta[b]pyrrole-2-carboxylic acid
dc.typeArticleen_US

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