Synthesis, characterization and catalytic behavior in the Suzuki reaction of Schiff base and its complexes and the optical properties of nickel complex used in the fabrication of a photodiode

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dc.contributor.authorPasa, Salih
dc.contributor.authorOcak, Yusuf Selim
dc.contributor.authorTemel, Hamdi
dc.contributor.authorKilicoglu, Tahsin
dc.date.accessioned2024-04-24T16:14:52Z
dc.date.available2024-04-24T16:14:52Z
dc.date.issued2013
dc.departmentDicle Üniversitesien_US
dc.description.abstractSchiff base ligand N,N'-bis(2-hydroxy-1-naphtaldehydene)-1,4-bis(o-amino phenilthio)butane (L) derived from 2-hydroxy-1-naphthaldehyde and 1,4-bis(o-amino thiophenol)butane was synthesized and characterized by FTIR-ATR, H-1 NMR, MS, TGA/DTA, elemental analysis, UV-Vis Spectroscopy. The reactions of the ligand with different transition metal(11) salts under reflux system condition afforded a series of metal complexes such as Cu(II), Co(III), Ni(II), Pd(II). Palladium-catalyzed Suzuki cross-coupling reactions employing Schiff-base as ligand toward a various of substituted arylbromides and boronic acids were pursued. The conversions obtained and yields with different arylbromides were calculated and summarized. The transmission and absorbance spectra of the Ni(II) complex were taken by UV-Vis spectrophotometer, and direct and indirect band gap values were determined by optical method. A photodiode was fabricated by forming a thin film on n-Si wafer and evaporating Au contact onto the film. It was seen that the structure has a good rectification. The electrical properties of the diode were calculated using current voltage measurements. Furthermore, the effect of light on current voltage measurements of the structure was examined using a solar simulator with AM1.5 filter at various illumination intensities. (C) 2013 Elsevier B.V. All rights reserved.en_US
dc.description.sponsorshipDicle University [DUBAP 08-EF-21, DUBAP 10-ZEF-28, DUBAP 10-ZEF-165]en_US
dc.description.sponsorshipFinancial support by the Dicle University (DUBAP 08-EF-21, DUBAP 10-ZEF-28 and DUBAP 10-ZEF-165) is gratefully acknowledged.en_US
dc.identifier.doi10.1016/j.ica.2013.02.038
dc.identifier.endpage504en_US
dc.identifier.issn0020-1693
dc.identifier.issn1873-3255
dc.identifier.scopus2-s2.0-84885310208
dc.identifier.scopusqualityQ2
dc.identifier.startpage493en_US
dc.identifier.urihttps://doi.org/10.1016/j.ica.2013.02.038
dc.identifier.urihttps://hdl.handle.net/11468/15458
dc.identifier.volume405en_US
dc.identifier.wosWOS:000324223200068
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoenen_US
dc.publisherElsevier Science Saen_US
dc.relation.ispartofInorganica Chimica Acta
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectSchiff Baseen_US
dc.subjectTransition Metal Complexesen_US
dc.subjectSuzuki Couplingen_US
dc.subjectOptical Propertiesen_US
dc.subjectRectifying Contacten_US
dc.subjectPhotodiodeen_US
dc.titleSynthesis, characterization and catalytic behavior in the Suzuki reaction of Schiff base and its complexes and the optical properties of nickel complex used in the fabrication of a photodiodeen_US
dc.titleSynthesis, characterization and catalytic behavior in the Suzuki reaction of Schiff base and its complexes and the optical properties of nickel complex used in the fabrication of a photodiode
dc.typeArticleen_US

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