Synthesis and characterization of cage structured flame resistant melamine and pentaerythritol based polymer networks

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dc.authorid0000-0002-9813-2962en_US
dc.authorid0000-0002-3728-1825en_US
dc.contributor.authorKaya, İsmet
dc.contributor.authorİriş, Ruhsar Ela
dc.contributor.authorYağmur, Hatice Karaer
dc.date.accessioned2023-10-27T08:18:12Z
dc.date.available2023-10-27T08:18:12Z
dc.date.issued2023en_US
dc.departmentDicle Üniversitesi, Fen Fakültesi, Kimya Bölümüen_US
dc.description.abstractIn this study, a Schiff base 2,4,6-tris(4-hidroksibenzimino)-1,3,5-triazine (HT) was synthesized from condensation reaction of 4-hydroxybenzaldehyde and melamine. Subsequently, various imine or ether bond cage polymers were synthesized using 2,4,6-tris(4-hydroxybenzimino)-1,3,5-triazine (HT), pentaerythritol (PT), 1,5-dibromopentane (DP), and p-xylylene dibromide (DX) in DMF. The structures of the compounds were characterized using FT-IR, 1 H, 13C-NMR and TGA measurements. The surface morphologies, particle ratious and the glass transition temperatures of polymers were found from SEM, DLS and DSC measurements, respectively. The melamine-based polymers PHTDX and PHTDP were synthesized from the monomer HT. Pentaerythritol-based PPTDX and PPTDP polymers were synthesized from the monomer PT. Melamine (M) and pentaerythritol are used in many applications, such as fire-resistant coatings and flame-retardant plastics. Thermally stable polymers were prepared with melamine and pentaerythritol. Based on SEM images, the polymers were found to have a porous structure. These pores make the polymers flame retardant by trapping combustible gases during thermal degradation. The limiting oxygen index values of PHTDX, PHTDP, PPTDX, and PPTDP at 1000 °C were reported to be 43.96, 40.42, 31.35 and 23.11, respectively, in TGA measurements.en_US
dc.description.sponsorshipCanakkale Onsekiz Mart University FYL-2018-2596en_US
dc.identifier.citationKaya, İ., İriş, R. E. ve Yağmur, H. K. (2023). Synthesis and characterization of cage structured flame resistant melamine and pentaerythritol based polymer networks. Journal of Polymer Research, 30(10), 1-15.en_US
dc.identifier.doi10.1007/s10965-023-03761-z
dc.identifier.endpage15en_US
dc.identifier.issn1022-9760
dc.identifier.issue10en_US
dc.identifier.scopus2-s2.0-85171629692
dc.identifier.scopusqualityQ2
dc.identifier.startpage1en_US
dc.identifier.urihttps://link.springer.com/article/10.1007/s10965-023-03761-z
dc.identifier.urihttps://hdl.handle.net/11468/12975
dc.identifier.volume30en_US
dc.identifier.wosWOS:001073500300001
dc.identifier.wosqualityN/A
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthorYağmur, Hatice Karaer
dc.language.isoenen_US
dc.publisherSpringer Science and Business Mediaen_US
dc.relation.ispartofJournal of Polymer Research
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectCage structured polymersen_US
dc.subjectMelamine-based Schiff baseen_US
dc.subjectPentaerythritolen_US
dc.subjectThermal degradationen_US
dc.titleSynthesis and characterization of cage structured flame resistant melamine and pentaerythritol based polymer networksen_US
dc.titleSynthesis and characterization of cage structured flame resistant melamine and pentaerythritol based polymer networks
dc.typeArticleen_US

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