Synthesis and characterizations of N,N-bis(diphenylphosphino)ethylaniline derivatives and X-ray crystal structure of palladium (II), platinum (II) complexes

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dc.contributor.authorDurap, Feyyaz
dc.contributor.authorBiricik, Nermin
dc.contributor.authorGuemguem, Bahattin
dc.contributor.authorOezkar, Saim
dc.contributor.authorAng, Wee Han
dc.contributor.authorFei, Zhaofu
dc.contributor.authorScopelliti, Rosario
dc.date.accessioned2024-04-24T16:18:17Z
dc.date.available2024-04-24T16:18:17Z
dc.date.issued2008
dc.departmentDicle Üniversitesien_US
dc.description.abstractN,N-Bis(diphenylphosphino)ethylaniline compounds, [Ph2P](2)N-C6H4-C2H5, with ethyl groups at the ortho- and para-positions have been synthesized. Oxidation of the aminophosphines with hydrogen peroxide, elemental sulfur and selenium gave the corresponding oxides, sulfides and selenides [Ph2P(E)](2)N-C6H4-C2H5 (E = O, S, Se). Complexes [MCl2{(Ph2P)(2)N-C6H4-(C2H5)}] (M = Pd, Pt) and [Cu{(Ph2P)(2)N-C6H4-C2H5)(2)]PF6 were obtained by the reaction of NN-bis(diphenylphosphino)ethylaniline with [MCl2(COD)] (M = Pd, Pt) and (Cu(MeCN)(4)]PF6. The new compounds were characterized by NMR, IR spectroscopy and microanalysis. In addition, representative solid-state structures of the palladium and platinum complexes were determined using single crystal X-ray diffraction analyses. (C) 2007 Elsevier Ltd. All rights reserved.en_US
dc.identifier.doi10.1016/j.poly.2007.09.011
dc.identifier.endpage202en_US
dc.identifier.issn0277-5387
dc.identifier.issue1en_US
dc.identifier.scopus2-s2.0-37349040766
dc.identifier.scopusqualityQ2
dc.identifier.startpage196en_US
dc.identifier.urihttps://doi.org/10.1016/j.poly.2007.09.011
dc.identifier.urihttps://hdl.handle.net/11468/15955
dc.identifier.volume27en_US
dc.identifier.wosWOS:000253191100025
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoenen_US
dc.publisherPergamon-Elsevier Science Ltden_US
dc.relation.ispartofPolyhedron
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectAminophosphineen_US
dc.subjectSynthesisen_US
dc.subjectOxidationen_US
dc.subjectComplexationen_US
dc.subjectX-Ray Structuresen_US
dc.titleSynthesis and characterizations of N,N-bis(diphenylphosphino)ethylaniline derivatives and X-ray crystal structure of palladium (II), platinum (II) complexesen_US
dc.titleSynthesis and characterizations of N,N-bis(diphenylphosphino)ethylaniline derivatives and X-ray crystal structure of palladium (II), platinum (II) complexes
dc.typeArticleen_US

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