Synthesis and Crystal Structure of Chiral Substituted (S)-2-[(4-Methoxyphenoxy) Methyl]-15-Crown-5 Ether with Sodium Perchlorate Complex

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dc.contributor.authorDogan, Nermin
dc.contributor.authorOzbey, Sueheyla
dc.contributor.authorKarakaplan, Mehmet
dc.contributor.authorAral, Tarik
dc.date.accessioned2024-04-24T16:02:14Z
dc.date.available2024-04-24T16:02:14Z
dc.date.issued2008
dc.departmentDicle Üniversitesien_US
dc.description.abstractThe crystal and molecular structure of chiral crown ether, (S)-2-[(4-methoxyphenoxy)methyl]-15-crown-5 center dot NaClO4, has been determined by single-crystal X-ray diffraction. The complex crystallizes in the orthorombic space group Pbca with Z = 8. Lattice parameters are a = 11.451(2), b = 12.842(3), c = 31.330(7) angstrom. The structure was refined to R factor of 0.0547. The Na ion is heptacoordinated. The Na-O-ether distances range from 2.363(4) to 2.433(4) degrees and average 2.404(5) degrees. Perchlorate anion is bounded to sodium ion asymmetrically; the Na-O8 and Na-O9 distances are 2.444(5) degrees and 2.607(5) degrees. The C-O and C-C distances of the 15-membered ring average 1.419(9) and 1.478(12) degrees while the O-C-C and C-O-C angles average 108.2(6)degrees and 115.4(6)degrees.en_US
dc.identifier.doi10.1007/s10870-008-9417-8
dc.identifier.endpage947en_US
dc.identifier.issn1074-1542
dc.identifier.issn1572-8854
dc.identifier.issue12en_US
dc.identifier.scopus2-s2.0-58549088297
dc.identifier.scopusqualityQ3
dc.identifier.startpage943en_US
dc.identifier.urihttps://doi.org/10.1007/s10870-008-9417-8
dc.identifier.urihttps://hdl.handle.net/11468/14705
dc.identifier.volume38en_US
dc.identifier.wosWOS:000259961100010
dc.identifier.wosqualityQ4
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoenen_US
dc.publisherSpringer/Plenum Publishersen_US
dc.relation.ispartofJournal of Chemical Crystallography
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectChiral Crown Etheren_US
dc.subjectSodium Complexen_US
dc.subject15-Crown-5en_US
dc.subjectCrystal Structureen_US
dc.titleSynthesis and Crystal Structure of Chiral Substituted (S)-2-[(4-Methoxyphenoxy) Methyl]-15-Crown-5 Ether with Sodium Perchlorate Complexen_US
dc.titleSynthesis and Crystal Structure of Chiral Substituted (S)-2-[(4-Methoxyphenoxy) Methyl]-15-Crown-5 Ether with Sodium Perchlorate Complex
dc.typeArticleen_US

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