New chiral phosphinite ligands with C2-symmetric axis and their possible applications in Ru-catalyzed asymmetric transfer hydrogenation

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dc.contributor.authorAydemir, Murat
dc.contributor.authorMeriç, Nermin
dc.contributor.authorBaysal, Akın
dc.contributor.authorKayan, Cezmi
dc.contributor.authorToğrul, Mahmut
dc.contributor.authorGümgüm, Bahattin
dc.contributor.orcid0000-0001-7294-6792
dc.contributor.orcid0000-0001-5700-8546
dc.date.accessioned2024-04-24T15:59:18Z
dc.date.available2024-04-24T15:59:18Z
dc.date.issued2010
dc.departmentDicle Üniversitesi, Fen Fakültesi, Kimya Bölümüen_US
dc.description.abstractThe new chiral ligands N,N'-bis-[(1R)-1-ethyl-2-O-(diphenylphosphinite)ethyl]ethanediamide, 1, and N,N'-bis-[(1S)-1-isobutyl-2-O-(diphenylphosphinite)ethyl]ethanediamide, 2, and the corresponding ruthenium complexes 3 and 4 were prepared and their structures were elucidated by a combination of multinuclear NMR spectroscopy, IR spectroscopy and elemental analysis. Following activation by NaOH, these chiral ruthenium complexes serve as catalyst precursors for the asymmetric transfer hydrogenation of acetophenone derivatives in iPrOH. The complexes 3 and 4 showed high catalytic activity but low selectivity in asymmetric transfer hydrogenation reactions. Copyright (C) 2009 John Wiley & Sons, Ltd.en_US
dc.description.sponsorshipDicle University [DUAPK 05-FF-27, DUBAP-07-01-22]en_US
dc.description.sponsorshipWe are deeply indebted to highly talented group of co-workers whose names are listed in the relevant references. Partial support from Dicle University (project numbers DUAPK 05-FF-27 and DUBAP-07-01-22) is gratefully acknowledged.en_US
dc.identifier.citationAydemir, M., Meriç, N., Baysal, A., Kayan, C., Toğrul, M. ve Gümgüm, B. (2010). New chiral phosphinite ligands with C2-symmetric axis and their possible applications in Ru-catalyzed asymmetric transfer hydrogenation. Applied Organometallic Chemistry, 24(3), 215-221.
dc.identifier.doi10.1002/aoc.1594
dc.identifier.endpage221en_US
dc.identifier.issn0268-2605
dc.identifier.issn1099-0739
dc.identifier.issue3en_US
dc.identifier.scopus2-s2.0-77449102846en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage215en_US
dc.identifier.urihttps://doi.org/10.1002/aoc.1594
dc.identifier.urihttps://hdl.handle.net/11468/13958
dc.identifier.urihttps://onlinelibrary.wiley.com/doi/epdf/10.1002/aoc.1594
dc.identifier.volume24en_US
dc.identifier.wosWOS:000275433700013en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.institutionauthorAydemir, Murat
dc.institutionauthorMeriç, Nermin
dc.institutionauthorBaysal, Akın
dc.institutionauthorKayan, Cezmi
dc.institutionauthorToğrul, Mahmut
dc.institutionauthorGümgüm, Bahattin
dc.language.isoenen_US
dc.publisherWileyen_US
dc.relation.ispartofApplied Organometallic Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectHomogeneous catalysisen_US
dc.subjectChiralityen_US
dc.subjectTransfer hydrogenationen_US
dc.subjectPhosphinite ligandsen_US
dc.subjectP-Cymene ruthenium(Ii) complexesen_US
dc.titleNew chiral phosphinite ligands with C2-symmetric axis and their possible applications in Ru-catalyzed asymmetric transfer hydrogenationen_US
dc.typeArticleen_US

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