The application of tunable tridendate P-based ligands for the Ru(II)-catalysed transfer hydrogenation of various ketones

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dc.contributor.authorMeriç, Nermin
dc.contributor.authorDurap, Feyyaz
dc.contributor.authorAydemir, Murat
dc.contributor.authorBaysal, Akın
dc.contributor.orcid0000-0001-7294-6792
dc.contributor.orcid0000-0003-0899-1948
dc.date.accessioned2024-04-24T15:59:19Z
dc.date.available2024-04-24T15:59:19Z
dc.date.issued2014
dc.departmentDicle Üniversitesi, Fen Fakültesi, Kimya Bölümüen_US
dc.description.abstractTwo novel versatile tridendate aminophosphine-phosphinite and phosphinite ligands were prepared and their trinuclear neutral ruthenium(II) dichloro complexes were found to be effective catalysts for the transfer hydrogenation of various ketones in excellent conversions up to 99% in the presence of 2-propanol/NaOH in 0.1M isopropanol solution. Particularly, [Ru-3(PPh2OC2H4)(2)N-PPh2((6)-p-cymene)(3)Cl-6] acts as an excellent catalyst giving the corresponding alcohols in excellent conversion up to 99% (turnover frequency1176h(-1)). A comparison of the catalytic properties of the complexes is also discussed briefly. Furthermore, the structures of these ligands and their corresponding complexes have also been clarified using a combination of multinuclear NMR spectroscopy, infrared spectroscopy and elemental analysis. H-1-C-13 HETCOR or H-1-H-1 COSY correlation experiments were used to confirm the spectral assignments. Copyright (c) 2014 John Wiley & Sons, Ltd.en_US
dc.description.sponsorshipDUBTAM; Dicle University (NMR project) [DUAPK 13-FF-113]en_US
dc.description.sponsorshipPartial support from DUBTAM and Dicle University (NMR project number: DUAPK 13-FF-113) is gratefully acknowledged.en_US
dc.identifier.citationMeriç, N., Durap, F., Aydemir, M. ve Baysal, A. (2014). The application of tunable tridendate P-based ligands for the Ru(II)-catalysed transfer hydrogenation of various ketones. Journal of Pharmacy and Pharmacology, 28(11), 803-808.
dc.identifier.doi10.1002/aoc.3202
dc.identifier.endpage808en_US
dc.identifier.issn0268-2605
dc.identifier.issn1099-0739
dc.identifier.issue11en_US
dc.identifier.scopus2-s2.0-84914810413
dc.identifier.scopusqualityQ1
dc.identifier.startpage803en_US
dc.identifier.urihttps://doi.org/10.1002/aoc.3202
dc.identifier.urihttps://hdl.handle.net/11468/13965
dc.identifier.urihttps://onlinelibrary.wiley.com/doi/epdf/10.1002/aoc.3202
dc.identifier.volume28en_US
dc.identifier.wosWOS:000344005400001
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthorMeriç, Nermin
dc.institutionauthorDurap, Feyyaz
dc.institutionauthorAydemir, Murat
dc.institutionauthorBaysal, Akın
dc.language.isoenen_US
dc.publisherWileyen_US
dc.relation.ispartofApplied Organometallic Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectAmppen_US
dc.subjectPhosphiniteen_US
dc.subjectRutheniumen_US
dc.subjectCatalysisen_US
dc.subjectTransfer hydrogenationen_US
dc.subjectKetoneen_US
dc.titleThe application of tunable tridendate P-based ligands for the Ru(II)-catalysed transfer hydrogenation of various ketonesen_US
dc.titleThe application of tunable tridendate P-based ligands for the Ru(II)-catalysed transfer hydrogenation of various ketones
dc.typeArticleen_US

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