Bimetallic PdxNi1-x and PdxCo1-x nanoparticles supported on K-OMS-2: Highly active, environmentally friendly and reusable nanocatalysts for the Suzuki–Miyaura cross-coupling reactions in water

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dc.contributor.authorDurap, Feyyaz
dc.contributor.authorGülen, Yasemin
dc.contributor.authorAbay, Ayşe
dc.contributor.authorBulut, Ahmet
dc.contributor.authorYurderi, Mehmet
dc.contributor.authorAydemir, Murat
dc.contributor.authorBaysal, Akın
dc.contributor.orcid0000-0003-0899-1948
dc.contributor.orcid0000-0002-5520-0558
dc.contributor.orcid0000-0001-5472-4213
dc.contributor.orcid0000-0002-1697-8623
dc.contributor.orcid0000-0002-0233-8940
dc.contributor.orcid0000-0002-4238-5012
dc.contributor.orcid0000-0001-7294-6792
dc.contributor.orcid0000-0002-5633-3811
dc.date.accessioned2024-04-24T15:59:19Z
dc.date.available2024-04-24T15:59:19Z
dc.date.issued2021
dc.departmentDicle Üniversitesi, Fen Fakültesi, Kimya Bölümüen_US
dc.description.abstractAddressed herein is the catalysis of bimetallic PdxNi1-x and PdxCo1-x nanoparticles (NPs) supported on a cryptomelane-type manganese oxide (K-OMS-2) solid for the Suzuki-Miyaura cross-couplings of phenylboronic acid with various aryl halides. Bimetallic PdxNi1-x and PdxCo1-x NPs were prepared by using a conventional one-step impregnation-reduction method. Among these catalysts with different compositions of Ni and Pd or Co and Pd, the Pd0.2Ni0.8 and Pd0.2Co0.8 catalysts showed the highest activity in the Suzuki-Miyaura cross-couplings of various aryl halides including iodides, bromides, and even chlorides with phenylboronic acid in ambient air and water under reflux conditions. The Suzuki-Miyaura cross-coupling reaction proceeded efficiently in the presence of Pd0.2Ni0.8@K-OMS-2 and Pd0.2Co0.8@K-OMS-2 NPs under the optimized conditions in water. Pd0.2Ni0.8@K-OMS-2 and Pd0.2Co0.8@K-OMS-2 NPs provided high conversions up to 98% and 99% and turnover frequencies of 11,760 and 11,880 h(-1) in the cross-coupling of phenylboronic acid with 1-bromo-4-nitrobenzene. More importantly, these new supported Pd0.2Ni0.8@K-OMS-2 and Pd0.2Co0.8@K-OMS-2 NPs were found to be highly durable nanocatalyst throughout the reusability experiments, and they maintain almost their inherent activity after 10th and 5th catalytic cycle, respectively. Bimetallic Pd0.2Ni0.8@K-OMS-2 and Pd0.2Co0.8@K-OMS-2 NPs were characterized by Fourier transform infrared spectroscopy (FT-IR), transmission electron microscopy (TEM), scanning electron microscopy with energy dispersive X-ray (SEM-EDX), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and ICAPQ inductively coupled plasma mass spectroscopy (ICP-MS) analyses.en_US
dc.description.sponsorshipDicle University Research Fund [FEN.20.001, FEN.18.014, FEN.18.009]en_US
dc.description.sponsorshipDicle University Research Fund, Grant/Award Numbers: FEN.20.001, FEN.18.014, FEN.18.009en_US
dc.identifier.citationDurap, F., Gülen, Y., Abay, A., Bulut, A., Yurderi, M., Aydemir, M. ve diğerleri. (2021). Bimetallic PdxNi1-x and PdxCo1-x nanoparticles supported on K-OMS-2: Highly active, environmentally friendly and reusable nanocatalysts for the Suzuki–Miyaura cross-coupling reactions in water. Applied Organometallic Chemistry, 35(2), 1-13.
dc.identifier.doi10.1002/aoc.6096
dc.identifier.endpage13
dc.identifier.issn0268-2605
dc.identifier.issn1099-0739
dc.identifier.issue2en_US
dc.identifier.scopus2-s2.0-85096895026
dc.identifier.scopusqualityQ1
dc.identifier.startpage1
dc.identifier.urihttps://doi.org/10.1002/aoc.6096
dc.identifier.urihttps://hdl.handle.net/11468/13974
dc.identifier.urihttps://onlinelibrary.wiley.com/doi/epdf/10.1002/aoc.6096
dc.identifier.volume35en_US
dc.identifier.wosWOS:000594922600001
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthorDurap, Feyyaz
dc.institutionauthorGülen, Yasemin
dc.institutionauthorAbay, Ayşe
dc.institutionauthorAydemir, Murat
dc.institutionauthorBaysal, Akın
dc.language.isoenen_US
dc.publisherWileyen_US
dc.relation.ispartofApplied Organometallic Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectBimetallic nanoparticlesen_US
dc.subjectC– C couplingen_US
dc.subjectGreen catalysten_US
dc.subjectHeterogeneous catalysten_US
dc.subjectManganese oxideen_US
dc.titleBimetallic PdxNi1-x and PdxCo1-x nanoparticles supported on K-OMS-2: Highly active, environmentally friendly and reusable nanocatalysts for the Suzuki–Miyaura cross-coupling reactions in wateren_US
dc.titleBimetallic PdxNi1-x and PdxCo1-x nanoparticles supported on K-OMS-2: Highly active, environmentally friendly and reusable nanocatalysts for the Suzuki–Miyaura cross-coupling reactions in water
dc.typeArticleen_US

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