Photochemical reactions of VIB and VIIB group metal carbonyl complexes with a chiral Schiff base
| dc.contributor.author | Subasi, Elif | |
| dc.contributor.author | Temel, Hamdi | |
| dc.date.accessioned | 2024-04-24T17:07:49Z | |
| dc.date.available | 2024-04-24T17:07:49Z | |
| dc.date.issued | 2007 | |
| dc.department | Dicle Üniversitesi | en_US |
| dc.description.abstract | The hitherto unknown complexes, [M(CO)(4)(eta(2)-H2L)], [M = Cr; 1, Mo; 2, W; 3]; fac-[Re(CO)(3)Br(eta(2)-H2L)], 4 and [(eta(5)-C5H5)Mn(CO)Br(eta(2)-H2L)], 5 have been synthesized by the photochemical reactions of VIB and VIIB metal carbonyls [M(CO)(6)] [M = Cr, Mo, W], Re(CO)(5)Br and (eta(5)-C5H5) Mn(CO)(3) with chiral Schiff base N,N'-bis-(2-hydroxynaphthalene-1-carbaldehydene)-(1R,2R)-(-)-diaminocyclohexane (H2L) in THF and characterized by elemental analyses, FTIR, H-1-NMR and mass spectra. The spectroscopic studies show that H2L ligand is coordinated to the central metal as a bidentate ligand coordinating via its imine nitrogens (C=N) in 1-5. | en_US |
| dc.identifier.doi | 10.1080/15533170601187409 | |
| dc.identifier.endpage | 89 | en_US |
| dc.identifier.issn | 1553-3174 | |
| dc.identifier.issn | 1553-3182 | |
| dc.identifier.issue | 2 | en_US |
| dc.identifier.scopus | 2-s2.0-33947198865 | |
| dc.identifier.scopusquality | N/A | |
| dc.identifier.startpage | 85 | en_US |
| dc.identifier.uri | https://doi.org/10.1080/15533170601187409 | |
| dc.identifier.uri | https://hdl.handle.net/11468/17019 | |
| dc.identifier.volume | 37 | en_US |
| dc.identifier.wos | WOS:000245787700003 | |
| dc.identifier.wosquality | Q3 | |
| dc.indekslendigikaynak | Web of Science | |
| dc.indekslendigikaynak | Scopus | |
| dc.language.iso | en | en_US |
| dc.publisher | Taylor & Francis Inc | en_US |
| dc.relation.ispartof | Synthesis and Reactivity in Inorganic Metal-Organic and Nano-Metal Chemistry | |
| dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
| dc.rights | info:eu-repo/semantics/closedAccess | en_US |
| dc.subject | N,N-Bis-(2-Hydroxynaphthalene-1-Carbaldehydene)- | en_US |
| dc.subject | (1r,2r)-(-)-Diaminocyclohexane | en_US |
| dc.subject | Metal Carbonyls | en_US |
| dc.subject | Schiff Base | en_US |
| dc.title | Photochemical reactions of VIB and VIIB group metal carbonyl complexes with a chiral Schiff base | en_US |
| dc.title | Photochemical reactions of VIB and VIIB group metal carbonyl complexes with a chiral Schiff base | |
| dc.type | Article | en_US |
