Aminophosphine-palladium(II) complexes: Synthsesis, structure and applications in Suzuki and Heck cross-coupling reactions

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dc.contributor.authorAydemir, Murat
dc.contributor.authorBaysal, Akin
dc.contributor.authorSahin, Ertan
dc.contributor.authorGumgum, Bahattin
dc.contributor.authorOzkar, Saim
dc.date.accessioned2024-04-24T16:14:52Z
dc.date.available2024-04-24T16:14:52Z
dc.date.issued2011
dc.departmentDicle Üniversitesien_US
dc.description.abstractReaction of furfurylamine with 1 or 2 equivalents of PPh2Cl in the presence of Et3N, proceeds under anaerobic conditions in thf to give furfuryl-2-(N-diphenylphosphino)amine, Ph2PNHCH2-C4H3O, 1 and furfuryl-2-(N,N-bis(diphenylphosphino)amine), (Ph2P)(2)NCH2-C4H3O, 2, respectively. The reactions of 1 and 2 with MCl2(cod) (M = Pd, Pt; cod = 1,5-cyclooctadiene) or Pt(CH3)(2)(cod) yield complexes [M(Ph2PNHCH2-C4H3O)(2)Cl-2] (M= Pd 1a, Pt 1b), [Pt(Ph2PNHCH2-C4H3O)(2)(CH3)(2)] (1c), and [M((Ph2P)(2) NCH2-C4H3O)Cl-2] (M= Pd 2a, Pt 2b), [Pt((Ph2P)(2)NCH2-C4H3O)(CH3)(2)] (2c), respectively. All the compounds were isolated as analytically pure substances and characterized by NMR, IR spectroscopy and elemental analysis. Representative solid-state structures of 2a and 2b were also determined by X-ray single crystal diffraction technique. Furthermore, the palladium complexes 1a and 2a were tested and found to be highly active catalysts in the Suzuki coupling and Heck reaction affording biphenyls and trans-stilbenes, respectively. (C) 2011 Elsevier B.V. All rights reserved.en_US
dc.description.sponsorshipDicle University [DUAPK 05-FF-27]; Turkish Academy of Sciencesen_US
dc.description.sponsorshipPartial support from Dicle University (Project No.: DUAPK 05-FF-27) and Turkish Academy of Sciences is gratefully acknowledged.en_US
dc.identifier.doi10.1016/j.ica.2011.07.056
dc.identifier.endpage18en_US
dc.identifier.issn0020-1693
dc.identifier.issn1873-3255
dc.identifier.issue1en_US
dc.identifier.scopus2-s2.0-80054987666
dc.identifier.scopusqualityQ2
dc.identifier.startpage10en_US
dc.identifier.urihttps://doi.org/10.1016/j.ica.2011.07.056
dc.identifier.urihttps://hdl.handle.net/11468/15455
dc.identifier.volume378en_US
dc.identifier.wosWOS:000296538000002
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoenen_US
dc.publisherElsevier Science Saen_US
dc.relation.ispartofInorganica Chimica Acta
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectAminophosphineen_US
dc.subjectFurfurylamineen_US
dc.subjectPalladiumen_US
dc.subjectPlatinumen_US
dc.subjectHeck Reactionen_US
dc.subjectSuzuki Couplingen_US
dc.titleAminophosphine-palladium(II) complexes: Synthsesis, structure and applications in Suzuki and Heck cross-coupling reactionsen_US
dc.titleAminophosphine-palladium(II) complexes: Synthsesis, structure and applications in Suzuki and Heck cross-coupling reactions
dc.typeArticleen_US

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