Synthesis and reactivity of bis(diphenylphosphino)amine ligands and their application in Suzuki cross-coupling reactions

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dc.contributor.authorKayan, Cezmi
dc.contributor.authorBiricik, Nermin
dc.contributor.authorAydemir, Murat
dc.contributor.authorScopelliti, Rosario
dc.date.accessioned2024-04-24T16:14:52Z
dc.date.available2024-04-24T16:14:52Z
dc.date.issued2012
dc.departmentDicle Üniversitesien_US
dc.description.abstractTwo new bis(diphenylphosphino) amines, N,N-bis(diphenylphosphino) benzidine 1 and N, N-bis(diphenylphosphino)- 3,3-dimethoxybenzidine 2 were prepared by aminolysis. Their corresponding oxides, sulfides and selenides were readily prepared by reaction with hydrogen peroxide, elemental sulfur or grey selenium, respectively. Symmetric dinuclear palladium and platinum complexes were also isolated from the reaction with [M(cod)Cl-2] (M = Pd or Pt, cod = cycloocta-1,5-diene). All compounds were characterized by IR and NMR spectroscopy and elemental analysis and the structure of [(Ph2P)(2)N-C6H4-C6H4-N(PPh2)(2)] was determined by single crystal X-ray diffraction. The catalytic activity of palladium complexes in Suzuki coupling reactions was also investigated. (C) 2012 Elsevier B.V. All rights reserved.en_US
dc.description.sponsorshipDicle University [DUBAP-06-FF-07]en_US
dc.description.sponsorshipFinancial support from Dicle University Research Fund (Project number: DUBAP-06-FF-07) is gratefully acknowledged.en_US
dc.identifier.doi10.1016/j.ica.2012.01.057
dc.identifier.endpage169en_US
dc.identifier.issn0020-1693
dc.identifier.issn1873-3255
dc.identifier.scopus2-s2.0-84858279652
dc.identifier.scopusqualityQ2
dc.identifier.startpage164en_US
dc.identifier.urihttps://doi.org/10.1016/j.ica.2012.01.057
dc.identifier.urihttps://hdl.handle.net/11468/15456
dc.identifier.volume385en_US
dc.identifier.wosWOS:000301455100022
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoenen_US
dc.publisherElsevier Science Saen_US
dc.relation.ispartofInorganica Chimica Acta
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectBis(Phosphino)Amineen_US
dc.subjectPalladium Complexen_US
dc.subjectX-Ray Structureen_US
dc.subjectCatalysisen_US
dc.subjectSuzuki Reactionen_US
dc.titleSynthesis and reactivity of bis(diphenylphosphino)amine ligands and their application in Suzuki cross-coupling reactionsen_US
dc.titleSynthesis and reactivity of bis(diphenylphosphino)amine ligands and their application in Suzuki cross-coupling reactions
dc.typeArticleen_US

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