Photochemical reactions of [M(CO)5THF] (M: Cr, Mo, and W) with tetradentate Schiff-bases

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dc.contributor.authorKarahan, Senem
dc.contributor.authorKose, Pelin
dc.contributor.authorSubasi, Elif
dc.contributor.authorTemel, Hamdi
dc.date.accessioned2024-04-24T17:07:49Z
dc.date.available2024-04-24T17:07:49Z
dc.date.issued2008
dc.departmentDicle Üniversitesien_US
dc.description.abstractThe new complexes, [(mu-CO)(2)Cr-2(4-H2L)(2)], 1; [(mu-CO)M-2(CO)(2)(eta(4)-H2L)(2)], [M = Mo; 2, W; 3]; [(mu-CO)(2)Cr-2(eta(4)-H2L')(2)], 4, and [(mu-CO)M-2(CO)(2)(eta(4)-H2L')(2)], [M = Mo; 5, W; 6] have been synthesized by the photochemical reactions of photogenerated intermediate, M(CO)(5)THF (M = Cr, Mo, W) with two oxygen and nitrogen donor Schiff base ligands, N,N'-bis(2-hydroxynaphtalin-1-carbaldehydene)-1,2-bis(p-aminophenoxy)ethane (H2L) and N,N'-bis(2-hydroxynaphtalin-1-carbalde-hydene)-1,4-bis(p-aminophenoxy)butane (H2L'). The complexes have been characterized by elemental analyses, LC-mass spectrometry, magnetic studies, FTIR, and H-1-NMR spectroscopy. The spectroscopic studies show that H2L and H2L' ligands are coordinated to the central metal as tetradentate ligands coordinating via their imine N and O donor atoms in (1-6).en_US
dc.description.sponsorshipResearch Foundation of Dokuz Eylul; Dicle University; Dokuz Eylul University [05. KB. FEN. 019]en_US
dc.description.sponsorshipWe thank the Research Foundation of Dokuz Eylul and Dicle University for funds. We thank TUBITAK for allocation of time at the Mass Spectra and Elemental Analyses. We thank Ege University for obtaining 1H-NMR spectra. This work was supported by Dokuz Eylul University, Project: 05. KB. FEN. 019.en_US
dc.identifier.doi10.1080/15533170802293303
dc.identifier.endpage619en_US
dc.identifier.issn1553-3174
dc.identifier.issn1553-3182
dc.identifier.issue7en_US
dc.identifier.scopus2-s2.0-51349148080
dc.identifier.scopusqualityN/A
dc.identifier.startpage615en_US
dc.identifier.urihttps://doi.org/10.1080/15533170802293303
dc.identifier.urihttps://hdl.handle.net/11468/17021
dc.identifier.volume38en_US
dc.identifier.wosWOS:000258979300010
dc.identifier.wosqualityQ4
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoenen_US
dc.publisherTaylor & Francis Incen_US
dc.relation.ispartofSynthesis and Reactivity in Inorganic Metal-Organic and Nano-Metal Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectN, N'-Bis(2-Hydroxynaphtalin-1-Carbaldehydene)-1,2-Bis(P-Aminophenoxy)Ethaneen_US
dc.subjectN, N'-Bis(2-Hydroxynaphtalin-1-Carbaldehydene)-1,4-Bis(P-Aminophenoxy)Butaneen_US
dc.subjectMetal Carbonylsen_US
dc.subjectSchiff Baseen_US
dc.titlePhotochemical reactions of [M(CO)5THF] (M: Cr, Mo, and W) with tetradentate Schiff-basesen_US
dc.titlePhotochemical reactions of [M(CO)5THF] (M: Cr, Mo, and W) with tetradentate Schiff-bases
dc.typeArticleen_US

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