Synthesis of cis-1,2-diol-type chiral ligands and their dioxaborinane derivatives: Application for the asymmetric transfer hydrogenation of various ketones and biological evaluation
dc.contributor.author | Kılıç, Ahmet | |
dc.contributor.author | Balcı, Tuğba Ersayan | |
dc.contributor.author | Arslan, Nevin | |
dc.contributor.author | Aydemir, Murat | |
dc.contributor.author | Durap, Feyyaz | |
dc.contributor.author | Okumuş, Veysi | |
dc.contributor.author | Tekin, Recep | |
dc.contributor.orcid | 0000-0001-9073-4339 | |
dc.contributor.orcid | 0000-0003-0899-1948 | |
dc.contributor.orcid | 0000-0002-4238-5012 | |
dc.contributor.orcid | 0000-0003-0142-9215 | |
dc.contributor.orcid | 0000-0002-5505-2700 | |
dc.contributor.orcid | 0000-0003-4577-4475 | |
dc.date.accessioned | 2024-04-24T15:59:19Z | |
dc.date.available | 2024-04-24T15:59:19Z | |
dc.date.issued | 2020 | |
dc.department | Dicle Üniversitesi, Fen Fakültesi, Kimya Bölümü | en_US |
dc.description.abstract | Two cis-1,2-diol-type chiral ligands (T-1 and T-2) and their tri-coordinated chiral dioxaborinane (T(1-2)B(1-2)) and four-coordinated chiral dioxaborinane adducts with 4-tert-butyl pyridine sustained by N -> B dative bonds (T(1-2)B(1-2)-N) were synthesized and characterized by various spectroscopic techniques such as NMR (H-1, C-13, and B-11), FT-IR and UV-Vis spectroscopy, LC-MS/MS, and elemental analysis. It was suggested that both ferrocene and trifluoromethyl groups played key roles in the catalytic and biological studies because they could tune the solubility of the chiral dioxaborinane complexes and adjust the strength of intermolecular interactions. To assess the biological activities of newly synthesized chiral dioxaborinane compounds, DPPH (2,2-diphenyl-1-picrylhydrazyl) radical scavenging, reducing power, antibacterial, DNA binding, and DNA cleavage activities were tested. Then, all chiral dioxaborinane complexes were investigated as catalysts for the asymmetric transfer hydrogenation of various ketones under suitable conditions. The results indicated that the chiral dioxaborinane catalysts performed well with high yields. | en_US |
dc.description.sponsorship | Research Fund of Harran University (HUBAP Projects) Sanliurfa, Turkey [19023] | en_US |
dc.description.sponsorship | We acknowledge gratefully the financial support from Research Fund of Harran University (HUBAP Projects No: 19023) Sanliurfa, Turkey. | en_US |
dc.identifier.citation | Kılıç, A., Balcı, T. E., Arslan, N., Aydemir, M., Durap, F., Okumuş, V. ve diğerleri. (2020). Synthesis of cis-1,2-diol-type chiral ligands and their dioxaborinane derivatives: Application for the asymmetric transfer hydrogenation of various ketones and biological evaluation. Applied Organometallic Chemistry, 34(10), 1-19. | |
dc.identifier.doi | 10.1002/aoc.5835 | |
dc.identifier.endpage | 19 | |
dc.identifier.issn | 0268-2605 | |
dc.identifier.issn | 1099-0739 | |
dc.identifier.issue | 10 | en_US |
dc.identifier.scopus | 2-s2.0-85085991294 | |
dc.identifier.scopusquality | Q1 | |
dc.identifier.startpage | 1 | |
dc.identifier.uri | https://doi.org/10.1002/aoc.5835 | |
dc.identifier.uri | https://hdl.handle.net/11468/13973 | |
dc.identifier.uri | https://onlinelibrary.wiley.com/doi/epdf/10.1002/aoc.5835 | |
dc.identifier.volume | 34 | en_US |
dc.identifier.wos | WOS:000537708200001 | |
dc.identifier.wosquality | Q1 | |
dc.indekslendigikaynak | Web of Science | |
dc.indekslendigikaynak | Scopus | |
dc.institutionauthor | Aydemir, Murat | |
dc.institutionauthor | Durap, Feyyaz | |
dc.institutionauthor | Tekin, Recep | |
dc.language.iso | en | en_US |
dc.publisher | Wiley | en_US |
dc.relation.ispartof | Applied Organometallic Chemistry | |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.subject | Asymmetric transfer hydrogenation | en_US |
dc.subject | Biological activitieschiral dioxaborinanescis-1 | en_US |
dc.subject | 2-diol-type chiral ligands | en_US |
dc.title | Synthesis of cis-1,2-diol-type chiral ligands and their dioxaborinane derivatives: Application for the asymmetric transfer hydrogenation of various ketones and biological evaluation | en_US |
dc.title | Synthesis of cis-1,2-diol-type chiral ligands and their dioxaborinane derivatives: Application for the asymmetric transfer hydrogenation of various ketones and biological evaluation | |
dc.type | Article | en_US |
Dosyalar
Orijinal paket
1 - 1 / 1
[ X ]
- İsim:
- Synthesis of cis-1,2-diol-type chiral ligands and their dioxaborinane derivatives Application for the asymmetric transfer hydrogenation of various ketones and biological evaluation.pdf
- Boyut:
- 7.23 MB
- Biçim:
- Adobe Portable Document Format
- Açıklama:
- Makale Dosyası