Synthesis of cis-1,2-diol-type chiral ligands and their dioxaborinane derivatives: Application for the asymmetric transfer hydrogenation of various ketones and biological evaluation

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dc.contributor.authorKılıç, Ahmet
dc.contributor.authorBalcı, Tuğba Ersayan
dc.contributor.authorArslan, Nevin
dc.contributor.authorAydemir, Murat
dc.contributor.authorDurap, Feyyaz
dc.contributor.authorOkumuş, Veysi
dc.contributor.authorTekin, Recep
dc.contributor.orcid0000-0001-9073-4339
dc.contributor.orcid0000-0003-0899-1948
dc.contributor.orcid0000-0002-4238-5012
dc.contributor.orcid0000-0003-0142-9215
dc.contributor.orcid0000-0002-5505-2700
dc.contributor.orcid0000-0003-4577-4475
dc.date.accessioned2024-04-24T15:59:19Z
dc.date.available2024-04-24T15:59:19Z
dc.date.issued2020
dc.departmentDicle Üniversitesi, Fen Fakültesi, Kimya Bölümüen_US
dc.description.abstractTwo cis-1,2-diol-type chiral ligands (T-1 and T-2) and their tri-coordinated chiral dioxaborinane (T(1-2)B(1-2)) and four-coordinated chiral dioxaborinane adducts with 4-tert-butyl pyridine sustained by N -> B dative bonds (T(1-2)B(1-2)-N) were synthesized and characterized by various spectroscopic techniques such as NMR (H-1, C-13, and B-11), FT-IR and UV-Vis spectroscopy, LC-MS/MS, and elemental analysis. It was suggested that both ferrocene and trifluoromethyl groups played key roles in the catalytic and biological studies because they could tune the solubility of the chiral dioxaborinane complexes and adjust the strength of intermolecular interactions. To assess the biological activities of newly synthesized chiral dioxaborinane compounds, DPPH (2,2-diphenyl-1-picrylhydrazyl) radical scavenging, reducing power, antibacterial, DNA binding, and DNA cleavage activities were tested. Then, all chiral dioxaborinane complexes were investigated as catalysts for the asymmetric transfer hydrogenation of various ketones under suitable conditions. The results indicated that the chiral dioxaborinane catalysts performed well with high yields.en_US
dc.description.sponsorshipResearch Fund of Harran University (HUBAP Projects) Sanliurfa, Turkey [19023]en_US
dc.description.sponsorshipWe acknowledge gratefully the financial support from Research Fund of Harran University (HUBAP Projects No: 19023) Sanliurfa, Turkey.en_US
dc.identifier.citationKılıç, A., Balcı, T. E., Arslan, N., Aydemir, M., Durap, F., Okumuş, V. ve diğerleri. (2020). Synthesis of cis-1,2-diol-type chiral ligands and their dioxaborinane derivatives: Application for the asymmetric transfer hydrogenation of various ketones and biological evaluation. Applied Organometallic Chemistry, 34(10), 1-19.
dc.identifier.doi10.1002/aoc.5835
dc.identifier.endpage19
dc.identifier.issn0268-2605
dc.identifier.issn1099-0739
dc.identifier.issue10en_US
dc.identifier.scopus2-s2.0-85085991294
dc.identifier.scopusqualityQ1
dc.identifier.startpage1
dc.identifier.urihttps://doi.org/10.1002/aoc.5835
dc.identifier.urihttps://hdl.handle.net/11468/13973
dc.identifier.urihttps://onlinelibrary.wiley.com/doi/epdf/10.1002/aoc.5835
dc.identifier.volume34en_US
dc.identifier.wosWOS:000537708200001
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthorAydemir, Murat
dc.institutionauthorDurap, Feyyaz
dc.institutionauthorTekin, Recep
dc.language.isoenen_US
dc.publisherWileyen_US
dc.relation.ispartofApplied Organometallic Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectAsymmetric transfer hydrogenationen_US
dc.subjectBiological activitieschiral dioxaborinanescis-1en_US
dc.subject2-diol-type chiral ligandsen_US
dc.titleSynthesis of cis-1,2-diol-type chiral ligands and their dioxaborinane derivatives: Application for the asymmetric transfer hydrogenation of various ketones and biological evaluationen_US
dc.titleSynthesis of cis-1,2-diol-type chiral ligands and their dioxaborinane derivatives: Application for the asymmetric transfer hydrogenation of various ketones and biological evaluation
dc.typeArticleen_US

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